Dehydrogenative Coupling of Thiol with Hydrosilane Catalyzed by an Iron Complex

Fukumoto, Kozo; Kasa, Michiho; Oya, Tsukuru; Itazaki, Masumi; Nakazawa, Hiroshi

doi:10.1021/om200377e

Cited by 30 publications

(19 citation statements)

References 25 publications

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“…Unsaturated E having an ER’ ligand tends to dimerize to produce saturated K , and they are in equilibrium. This type of equilibrium and the related catalytic cycle for Si‐S bond formation have been reported . Therefore, the catalytic pathway to form an Sn–S and Sn–Se bond shown in Scheme seems to be reasonable.…”

Section: Resultssupporting

confidence: 90%

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Dehydrogenative Sn–E (E = S, Se) bond formation catalyzed by an iron complex

Itazaki

Ogawa

Nakamura

et al. 2018

Heteroatom Chemistry

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Section: Resultssupporting

confidence: 90%

“…Previously, we reported dehydrogenative coupling of thiol with hydrosilane catalyzed by an iron complex (Scheme ), in which the corresponding Si–S coupling products were obtained in low to excellent yields.…”

Section: Introductionmentioning

confidence: 99%

Dehydrogenative Sn–E (E = S, Se) bond formation catalyzed by an iron complex

Itazaki

Ogawa

Nakamura

et al. 2018

Heteroatom Chemistry

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“…The generalized formation of carbon-heteroatom and heteroatom-heteroatom bonds is depicted in Scheme 4, along with some prototypical examples [53][54][55]. The chemistry is discussed in detail by Jean-Luc Renaud in [52].…”

Section: C-heteroatom and Heteroatom-heteroatom Bondforming Reactionsmentioning

confidence: 99%

Iron Catalysis: Historic Overview and Current Trends

Bauer

2015

Topics in Organometallic Chemistry

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Iron catalysis is a growing area of research, as seen by an exponential increase in the publication activities on the topic. This introductory chapter provides a historic overview of the development of iron catalysis including some notable milestones. The advantages of iron, i.e., its abundance, low price, and relative nontoxicity, are discussed, and an overview of the main type of reactions catalyzed by iron is outlined. The advances of heterogeneous iron catalysis (which is not covered in this volume) are exemplified with a few notable cases. Finally, the potential impact of metal impurities in iron sources on the catalytic activity is discussed.

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“…2 ] in the reaction of hydrosilanes with thioalcohols was also reported. This reaction selectively creates a Si-S bond (Scheme 47) [72]. Dehydrogenative coupling of hydrosilanes and thiols catalyzed by a transition metal complex has attracted less attention mainly because catalyst poisoning by sulfur was a major deterrence.…”

Section: E-e Cdc Reactionmentioning

confidence: 99%

Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions

Itazaki

Nakazawa

2015

Topics in Organometallic Chemistry

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Cross-dehydrogenative-coupling (CDC) reactions involving C-H bond activation are powerful tools for C-C bond formation and are highly significant from the perspective of atom economy. A variety of carbon-carbon bond-forming reactions utilizing various coupling partners are known today. Iron-catalyzed organic syntheses have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. This chapter summarizes the development of iron-catalyzed CDC reactions, the reaction mechanism, and the role of the Fe species in the catalytic cycle in the period from 2007 to 2014.

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Dehydrogenative Coupling of Thiol with Hydrosilane Catalyzed by an Iron Complex

Cited by 30 publications

References 25 publications

Dehydrogenative Sn–E (E = S, Se) bond formation catalyzed by an iron complex

Dehydrogenative Sn–E (E = S, Se) bond formation catalyzed by an iron complex

Iron Catalysis: Historic Overview and Current Trends

Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions

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