Abstract:We fabricated single-layer graphene
as an ideal two-dimensional
electrode for evaluating fundamental mechanism of ion transfer into
a capacitance system and conducted cyclic voltammetry and molecular
dynamics simulations to evaluate its capacitive performances in different
aqueous electrolytes solutions of KCl, NaBr, NaCl, NaF, and LiCl.
The system of KCl electrolyte had the highest areal capacitance at
various scan rates and the fast ion diffusion coefficient. The highest
capacitance and the fast ion diffusio… Show more
“…[13][14][15][16][17][18] Faster diffusion of K + ions associated with their desolvation on graphene and conical electrodes leads to high EDLC performance. 19,20 Furthermore, solvent dynamics has been reported to affect the EDLC performance in a narrow pore. 19 However, inuence of ion dynamics is still not well understood, and differences in the pore structure lead to discrepancies between experiments and simulations.…”
Electrical double-layer capacitance was reduced not only by degradation of ions, but also by the presence of idle ions. Meanwhile, the fast relaxation of capacitance and slow ion dynamics facilitate charge–discharge efficiency in wide pores.
“…[13][14][15][16][17][18] Faster diffusion of K + ions associated with their desolvation on graphene and conical electrodes leads to high EDLC performance. 19,20 Furthermore, solvent dynamics has been reported to affect the EDLC performance in a narrow pore. 19 However, inuence of ion dynamics is still not well understood, and differences in the pore structure lead to discrepancies between experiments and simulations.…”
Electrical double-layer capacitance was reduced not only by degradation of ions, but also by the presence of idle ions. Meanwhile, the fast relaxation of capacitance and slow ion dynamics facilitate charge–discharge efficiency in wide pores.
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