Fe-doped TiO 2 particles responding to visible light were synthesized by impregnation and calcination method using TiO 2 particle and Ti element, respectively. The optical and the chemical properties were characterized by measuring the X-ray diffraction (XRD) and UV-visible spectroscopy. The onset of absorption shifted to longer wavelengths on doping TiO 2 by the calcination process, which showed a better response as compared to the impregnation method. The photocatalytic reactivity was evaluated by the degradation of phenol with impregnated Fe-doped (0.5% w/w in Fe) and calcined Fe-doped (Fe x Ti 1Àx O 2 , x ¼ 0.005 (Fe/Ti molar ratio)) TiO 2 separately in distilled and tap water. The characterization results have confirmed the advanced possibility of correlation between photoactivity and the special property of sulfur-containing calcined Fe-doped TiO 2 . In case of the coagulation of the undoped A-I and the Fe-doped B-I, the photoactivity showed a decrease due to the presence of natural electrolytes and due to the high pH of tap water, whereas in the case of the coagulation of calcined Fe-doped TiO 2 prepared from sulfides (Fe x TiS 2 ), the photoactivity showed an increase. In this study, highest catalytic activity was found to be strongly dependent both on catalyst structure and on the type of water used.