The chemical composition of the second phase precipitation in the vacuum diffusion-bonded zone of Fe 3 Al intermetallic compound and Q235 carbon steel was analysed by means of electron probe microanalyser (EPMA). The relative content of the second phase precipitation and grain size was evaluated through a micro-image analyser. The percentage of Fe and Al content in the diffusion zone was measured by EPMA. The results indicated that the relative content of the second phase precipitation rich in carbon and chromium at the Fe 3 Al/Q235 interface was much higher. With the transition from Fe 3 Al intermetallic compound to Q235 carbon steel across Fe 3 Al/Q235 interface, the grain diameter decreased from 250 µm to 112 µm, Al atom content decreased from 27% to 15%, while Fe atom content increased from 76% to 96%. Keywords. Fe 3 Al/Q235 diffusion-bonded zone; vacuum diffusion bonding.