Defect-Driven Efficient Selective CO₂ Hydrogenation with Mo-Based Clusters

Abstract

Synthetic fuels produced from CO 2 show promise in combating climate change. The reverse water gas shift (RWGS) reaction is the key to opening the CO 2 molecule, and CO serves as a versatile intermediate for creating various hydrocarbons. Mo-based catalysts are of great interest for RWGS reactions featured for their stability and strong metal−oxygen interactions. Our study identified Mo defects as the intrinsic origin of the high activity of cluster Mo 2 C for CO 2 -selective hydrogenation. Specifically, we found that defected Mo 2 C clusters supported on nitrogen-doped graphene exhibited exceptional catalytic performance, attaining a reaction rate of 6.3 g CO /g cat /h at 400 °C with over 99% CO selectivity and good stability. Such a catalyst outperformed other Mo-based catalysts and noble metal-based catalysts in terms of facile dissociation of CO 2 , highly selective hydrogenation, and nonbarrier liberation of CO. Our study revealed that as a potential descriptor, the atomic magnetism linearly correlates to the liberation capacity of CO, and Mo defects facilitated product desorption by reducing the magnetization of the adsorption site. On the other hand, the defects were effective in neutralizing the negative charges of surface hydrogen, which is crucial for selective hydrogenation. Finally, we have successfully demonstrated that the combination of a carbon support and the carbonization process synergistically serves as a feasible strategy for creating rich Mo defects, and biochar can be a low-cost alternative option for large-scale applications.

Recent Advances in the Reverse Water–Gas Conversion Reaction

“…Molybdenum is more abundant and cheaper than precious metals, increasing the potential for large−scale industrial applications of molybdenum−based catalysts. Molybdenum− containing catalysts are widely used, including Ni−Mo catalysts [132], molybdenum sulfide catalysts [133], MoO x catalysts [54], supported Mo-based catalysts [55,134], new Mo 2 C and Mo 2 N catalysts [135], etc. A few representative examples are described below.…”