The National Aeronautics and Space Administration's (NASA) Deep Space Optical Communications (DSOC) payload, launched with the Psyche spacecraft on October 13, 2023, is facilitating an ongoing technology demonstration (TD) of free-space optical communications (FSOC), from beyond the earth-moon system. The DSOC flight laser transceiver (FLT), can acquire a 1064 nm uplink laser from earth, and return a 1550 nm, serially concatenated pulse position modulated (SCPPM) signal, to earth. The FLT uses a 22 cm diameter unobscured optical transceiver assembly, coupled to a 4 W average power laser transmitter, supplemented with actuators, sensors, electronics and software. A 5-7 kW average power, multi-beam 1064 nm uplink laser assembly integrated to the Optical Communications Telescope Laboratory (OCTL) near Wrightwood, CA serves as the Ground Laser Transmitter (GLT). The DSOC Ground Laser Receiver (GLR) at the Palomar Observatory, Hale telescope (operated by Caltech Optical Observatories), consists of a superconducting nanowire single photon detector (SNSPD) array, connected to a ground signal processing assembly. Signal photon arrivals are detected and processed to extract information codewords at the GLR. A Mission Operations System (MOS) co-located with the Psyche Project Mission Operations Center, at the Jet Propulsion Laboratory (JPL), coordinates DSOC technology demonstration activities. This paper presents a system overview, mission description and operations architecture for the TD. Early results that include downlink at maximum downlink data-rate of 267 Mb/s from 0.37 astronomical units (AU) or 55 million kilometers are presented.