Decoupling Substitution Effects from Point Defects in Layered Ni‐Rich Oxide Cathode Materials for Lithium‐Ion Batteries
Leonhard Karger,
Svetlana Korneychuk,
Sabrina Sicolo
et al.
Abstract:Ni‐rich LiNixCoyMnzO2 cathode materials offer high practical capacities and good rate capability, but are notorious for being unstable at high state of charge. Here, a series of such layered oxides with nickel contents ranging from 88 to 100 mol% is fabricated by sodium‐to‐lithium ion exchange, yielding materials devoid of substitutional defects. Examining the initial charge/discharge cycle reveals effects that are specifically caused by transition‐metal substitution, which would otherwise be obscured by chan… Show more
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