Abstract:4,4‐difluoro‐5,7‐dimethyl‐4‐bora‐3a,4a‐diaza‐s‐indacene (BODIPY) and derivatives are an outstanding class of fluorescent dyes. Herein, we report on the introduction of a nitrosyl moiety into the BODIPY structure and its dramatic effect on the observed electrochemical reaction mechanism. 6‐Nitrosyl‐8‐phenyl‐BODIPY and its 5‐nitrosyl positional isomer, compounds 2 and 3, respectively, were obtained from the meso precursor, 8‐phenyl‐BODIPY (1), by nitrosation. Electrochemical studies for 1–3 are reported. Cyclic … Show more
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