Decomposition of pentamethyltetrazenium iodide in water

Bruning, W. H.; Michejda, Christopher J.; Romans, D.

doi:10.1039/c19670000011

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“…The title compound was obtained as a colorless powder (0.295 g, 97%) and no further purification was necessary. (11), 245 (5), 327 (26), 364 (7), 426(4), 502 (12), 541(5), 620(2), 711(1), 820(3), 898 (33), 952(3), 1005 (6), 1064(1), 1106 (24), 1375 (35), 1385(100), 1452 (18) (E)-1,1,1,4,4-Pentamethyl-2-tetrazenium iodide (4) 50 . Compound 1 (1.290 mL, 1.16 g, 9.99 mmol) was loaded in a 10 mL round-bottom flask and cooled to 0 1C by means of a water/ice bath.…”

Section: General Methodsmentioning

confidence: 99%

Synthesis and stability of 2-tetrazenium salts

Sabaté

Delalu

2011

New J. Chem.

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Section: General Methodsmentioning

confidence: 99%

Synthesis and stability of 2-tetrazenium salts

Sabaté

Delalu

2011

New J. Chem.

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Ionization Potential, Oxidation Potential Comparisons for Compounds Containing Amino Nitrogen

Nelsen¹

1979

Israel Journal of Chemistry

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Plots of solution oxidation potential (E"', V vs SCE in acetonitrile) versus vapor phase vertical ionization potential (IF" eV) are discussed for several types of compounds containing amino nitrogen, including tetraalkylhydrazines, tetraalkyl-2tetrazenes, bicyclic diamines, and ortho and para-substituted phenylenediamines. All amino compounds fall considerably below the polycyclic aromatic hydrocarbon line in an EO' vs IF, plot, and there is not a linear correlation of EO' vs IF, for amino compounds. Reasons for the non-linearity, and the information that can be gained by comparison of the ease of electron removal in the vapor and solution phases are discussed.Vapor sotunoñ· T···. .

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19.4.1 Alkyl and H-substituted hydrazines

Nelsen¹

Organic Cation Radicals and Polyradicals. Index of Substances for Volumes II/1 and II/9

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Decomposition of pentamethyltetrazenium iodide in water

Cited by 5 publications

References 0 publications

Synthesis and stability of 2-tetrazenium salts

Synthesis and stability of 2-tetrazenium salts

Ionization Potential, Oxidation Potential Comparisons for Compounds Containing Amino Nitrogen

19.4.1 Alkyl and H-substituted hydrazines

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