Decomposition of fluorosilicone stationary phases in solution

Glass-catalyzed decomposition of oxycarboxin in aqueous solution

“…Interaction may be in the form of reaction with the container surface or adsorption to it; however, there are many more examples of the latter in the chemical literature. An example of a material reacting with the surface of a container was reported by Hanneman and Klimisch (1972). The study described the decomposition of organopolysiloxanes in acetone solution catalyzed by the surface of glass containers and how storage in polyethylene containers significantly reduced the rate of decomposition.…”