Decomposition kinetics of manganese tris (carbohydrazide) perchlorate (MnCP) derived from the filament control voltage of the T-jump/FTIR spectroscopy

A screened hybrid density functional study on energetic complexes: Cobalt, nickel and copper carbohydrazide perchlorates

“…From these previously reported experimental results [11][12][13][14][15][16][17][18][19][20], we find that, the stretching vibrations of the coordinated amino groups of the CHZ complexes are shifted to lower wave number compared with those of free CHZ ligand. Moreover, perchlorate complexes containing different metal atoms have obvious differences in properties such as thermal stability and impact sensitivity.…”

“…Transition metal perchlorate complexes with nitrogen-rich ligands have attracted considerable attention, since they have superior explosive performances and can be widely used as lead-free primary explosives [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20]. Carbohydrazide (CHZ) is an interesting azotic ligand with several lone-pair electrons.…”

“…Carbohydrazide (CHZ) is an interesting azotic ligand with several lone-pair electrons. The structures and properties of its energetic complexes have been extensively studied experimentally [11][12][13][14][15][16][17][18][19][20]. There are two different cases for coordination of the CHZ ligand in transition metal CHZ perchlorates.…”

Thermal Investigation and Kinetic Modeling of Lignocellulosic Biomass Combustion for Energy Production and Other Applications

“…The Arrhenius equation describes the temperature-dependent function in terms of the activation energy ( E a ) and the pre-exponential factor ( k 0 ) as in eq . , where E a is the activation energy in kJ mol –1 , T the absolute temperature in Kelvin, R the gas constant (8.314 J K –1 mol –1 ), and k 0 the pre-exponential factor (min –1 ).…”

“…Arrhenius equation describes the temperature dependent function in terms of the activation energy (Ea) and the pre-exponential factor (k 0 ) as in Equation 3 55,56 .…”