Abstract:Decoherence has been the basis for understanding the emergence of the classical world from its quantum underpinnings. Unfortunately the calculations establishing decoherence overshoot and, based on assumptions that break down, predict that with the passage of time the off-diagonal elements of the density matrix become arbitrarily small. It has been recognized by some authors that the thermal state, assumed to hold for systems in equilibrium, places a bound on off diagonal terms. In this article we establish-pr… Show more
“…The case of strong coupling is more tricky because of the possibility of steady-state coherences in the system's energy eigenbasis [36]. Nevertheless, there are small quantum systems of significant interest that are rigorously shown to approach the Gibbs state as an attractor, even with strong interactions [37,38].…”
Section: Appendix E: Justification For Approach To the Gibbs State Un...mentioning
Herein we provide a new exact result about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales. In particular, we show that the contraction of the quantum state-towards the minimally-dissipative trajectory-exactly quantifies the excess of thermodynamic dissipation during any finite-time transformation. The quantum component of this dissipation is the change in coherence relative to the minimally-dissipative state. Implications for quantum state preparation, local control, and decoherence are explored. For logically-irreversible processes-like the preparation of any particular quantum state-we find that mismatched expectations lead to divergent dissipation as the actual initial state becomes orthogonal to the anticipated one.
“…The case of strong coupling is more tricky because of the possibility of steady-state coherences in the system's energy eigenbasis [36]. Nevertheless, there are small quantum systems of significant interest that are rigorously shown to approach the Gibbs state as an attractor, even with strong interactions [37,38].…”
Section: Appendix E: Justification For Approach To the Gibbs State Un...mentioning
Herein we provide a new exact result about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales. In particular, we show that the contraction of the quantum state-towards the minimally-dissipative trajectory-exactly quantifies the excess of thermodynamic dissipation during any finite-time transformation. The quantum component of this dissipation is the change in coherence relative to the minimally-dissipative state. Implications for quantum state preparation, local control, and decoherence are explored. For logically-irreversible processes-like the preparation of any particular quantum state-we find that mismatched expectations lead to divergent dissipation as the actual initial state becomes orthogonal to the anticipated one.
“…In this article we do not fully solve the problem, but report ideas that lead to a resolution of sorts. In an appendix to a previous paper [5] we assumed the wave function was gaussian and that measurement caused a resumption of localization. In that heuristic treatment the size of a wave packet was on the order of √ th where the thermal wavelength is th = ℏ∕…”
We show that in a dilute gas the wave function's spreading is limited by scattering off other particles. This shows that quantum mechanics can be consistent with the kinetic theory of gases.
“…I do not deal with the effects of temperature (cf. [5]), nor with off-diagonal elements of the density matrix [6,7]. I am concerned with pure quantum behavior.…”
Under pure quantum evolution, for a wave packet that diffuses (like a Gaussian), scattering can cause localization. Other forms of the wave function, spreading more rapidly than a Gaussian, are unlikely to localize.
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