Deactivation of inhibitors (nitric oxide, alkylnitriles) in the interaction with the monomer (methyl methacrylate)

Leplyanin, G. V.; Antonova, L.F.; Rafikov, S. R.; Faizullov, R. R.; Zaev, E. E.; Ponomareva, V. A.; Grechishnikov, Yu. G.

doi:10.1007/bf00920672

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“…[21][22][23][24] In these cases, the formation of the vicinal dinitrosoalkanes were assisted by the metal. The formation of such ''free'' organic compounds (e.g., 15) has been invoked in the reaction of nitric oxide with methyl methacrylate during the formation of the nitro nitroso final product, 25 and a patent 26 claims the preparation of 1,2-dinitrosoperfluoroethane and 1,2-dinitrosotrifluoromonochloroethane from the reaction of the appropriate fluoroalkene with nitric oxide in the presence of infrared radiation. The preparation of difluorodinitrosomethane (ONCF 2 NO) 27 from the photolysis of a mixture of CF 2 I 2 and NO is the first report of a geminal dinitroso compound, but it lacks thermal stability and is light-sensitive.…”

Section: Non-interacting Dinitroso Compoundsmentioning

confidence: 99%

“…The polymeric p-dinitrosobenzenes identified are based upon the monomer unit(25) where X = Y = Z = H, 36,63,65-71 X = CH 3 and Y = Z = H, 66,72-74 X = OCH 3 and Y = Z = H, 75 X = Y = CH 3 and Z = H, 71,76 X = Z = CH 3 and Y = H, 71 X = CH 3 and Y = Cl and Z = H, 77 X = CH 3 and Y = i-Pr and Z = H, 66,71,74,78 X = Y = t-Bu and Z = H, 71 and X = Y = i-Pr and Z = H.…”

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confidence: 99%

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Dinitroso and polynitroso compounds

Gowenlock

Richter‐Addo

2005

Chem. Soc. Rev.

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The growing interest in the chemistry of C-nitroso compounds (RN=O; R = alkyl or aryl group) is due in part to the recognition of their participation in various metabolic processes of nitrogen-containing compounds. C-Nitroso compounds have a rich organic chemistry in their own right, displaying interesting intra- and intermolecular dimerization processes and addition reactions with unsaturated compounds. In addition, they have a fascinating coordination chemistry. While most of the attention has been directed towards C-nitroso compounds containing a single -NO moiety, there is an emerging area of research dealing with dinitroso and polynitroso compounds. In this critical review, we present and discuss the synthetic routes and properties of these relatively unexplored dinitroso and polynitroso compounds, and suggest areas of further development involving these compounds. (126 references.).

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