De novo synthesis and particle size control of iron metal organic framework for diclofenac drug delivery

So, Pamela Berilyn; Chen, Hsin‐Tsung; Lin, Chia Her

doi:10.1016/j.micromeso.2020.110495

Cited by 35 publications

(11 citation statements)

References 43 publications

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“…In this study, MIL-88B(Fe) (1,4-NDC), MIL-100(Fe), MIL-88B(Fe) (1,4-BDC), and Fe-1,4-NDC MOF were synthesized using procedures reported in the literature. [38][39][40] However, the MIL-88B(Fe) (1,4-NDC) MOF was synthesized using a solvothermal method with a specific combination of dimethyl formamide (DMF), methanol, and water. DMF played a crucial role in controlling the rate of deprotonation and nucleation during the synthesis of MIL-88B(Fe) (1,4-NDC) MOF, and an appropriate amount was added to the reaction mixture.…”

Section: Resultsmentioning

confidence: 99%

Exploring the potential of iron-based metal–organic frameworks as peroxidase nanozymes for glucose detection with various secondary building units

et al. 2023

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Section: Resultsmentioning

confidence: 99%

Exploring the potential of iron-based metal–organic frameworks as peroxidase nanozymes for glucose detection with various secondary building units

et al. 2023

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“…[ 71–73 ] In the solvothermal reaction process, choosing a suitable solvent is very important. Up to now, lots of organic‐solvents are employed to fabricate MOFs and their composites, including N , N ‐dimethylformamide (DMF), [ 74–76 ] N , N ‐diethylformamide (DEF), [ 77,78 ] dimethylsulfoxide (DMSO), [ 79–81 ] toluene, etc. During the synthesis process, these organic solvents act as a structure‐directing agent and synthesis media.…”

Section: The Synthesis Strategies Of the Mofs And Their Composites‐based Photocatalystsmentioning

confidence: 99%

“…In addition, many reports also demonstrated that the MOFs and their composites with different sizes (length, width or diameter) and morphologies can be synthesized through the solvothermal method, for instance, the polyhedral PCN‐250‐Fe 3 with a size of ≈13 µm, [ 72 ] the octahedral Uio‐68 and Uio‐68‐TZDC with the sizes from 10 to 20 µm, [ 73 ] the octahedral Co‐MOFs and Ni‐MOFs composite with an average size of ≈200 nm, [ 74 ] the rod‐shaped MIL‐53(Fe) with the length of ≈50 µm, [ 75 ] the octahedral MIL‐100(Fe) with the sizes from 100 to 200 nm, [ 79 ] etc.…”

Section: The Synthesis Strategies Of the Mofs And Their Composites‐based Photocatalystsmentioning

confidence: 99%

A Review of MOFs and Their Composites‐Based Photocatalysts: Synthesis and Applications

Qian

Zhang

Pang

2021

Adv Funct Materials

323

157

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Photocatalysis is considered to be a green and environment‐friendly technology since it can convert solar energy into other types of chemical energies. Over the past several years, metal‐organic frameworks (MOFs)‐based photocatalysts have received remarkable research interest due to their unique morphology, high photocatalytic performance, good chemical stability, easy synthesis, and low cost. In this review, the synthetic strategies of developing MOFs‐based photocatalysts are first introduced. Second, the recent progress in the fabrication of various types of MOFs composites photocatalysts is summarized. Third, the different applications including hydrogen evolution reaction, oxygen evolution reaction, overall water splitting, nitrogen reduction reaction, carbon dioxide reduction reaction as well as photodegradation of organic pollutants of MOFs‐based photocatalysts are summed up. Finally, the challenges and some suggestions for the future development of MOFs‐ and their composites‐based photocatalysts are also highlighted. It is expected that this report will help researchers to systematically devise and develop highly efficient photocatalysts based on MOFs and their composites.

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“…The selection of exchangeable molecules and size adjustment is essential, as MOF pores must be filled with important molecules in order to synthesize materials. In this context, the control of structure topology is defined by an adequate choice of connectors and binders [23,42,43].…”

Section: Metal-organic Frameworkmentioning

confidence: 99%

A Comprehensive Review on the Use of Metal–Organic Frameworks (MOFs) Coupled with Enzymes as Biosensors

et al. 2022

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Several studies have shown the development of electrochemical biosensors based on enzymes immobilized in metal–organic frameworks (MOFs). Although enzymes have unique properties, such as efficiency, selectivity, and environmental sustainability, when immobilized, these properties are improved, presenting significant potential for several biotechnological applications. Using MOFs as matrices for enzyme immobilization has been considered a promising strategy due to their many advantages compared to other supporting materials, such as larger surface areas, higher porosity rates, and better stability. Biosensors are analytical tools that use a bioactive element and a transducer for the detection/quantification of biochemical substances in the most varied applications and areas, in particular, food, agriculture, pharmaceutical, and medical. This review will present novel insights on the construction of biosensors with materials based on MOFs. Herein, we have been highlighted the use of MOF for biosensing for biomedical, food safety, and environmental monitoring areas. Additionally, different methods by which immobilizations are performed in MOFs and their main advantages and disadvantages are presented.

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De novo synthesis and particle size control of iron metal organic framework for diclofenac drug delivery

Cited by 35 publications

References 43 publications

Exploring the potential of iron-based metal–organic frameworks as peroxidase nanozymes for glucose detection with various secondary building units

Exploring the potential of iron-based metal–organic frameworks as peroxidase nanozymes for glucose detection with various secondary building units

A Review of MOFs and Their Composites‐Based Photocatalysts: Synthesis and Applications

A Comprehensive Review on the Use of Metal–Organic Frameworks (MOFs) Coupled with Enzymes as Biosensors

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