[DDQM][TFSI]: a room temperature ionic liquid as an active electrode material for supercapacitor devices and a catalyst for rapid synthesis of 4-aryl-NH-1,2,3-triazoles under microwave irradiation

Abstract

A multifunctional room temperature ionic liquid [DDQM][TFSI] has been designed and its properties have been investigated to be used as an electrolyte. The RTIL bears superior catalytic properties as well...

Ionic liquids for the green synthesis of 1,2,3-triazoles: a systematic review

“…Dutta et al also reported a newer and green approach for obtaining 1,2,3-triazoles ( 57a–57j ), in which various benzaldehyde derivatives were reacted with nitromethane and sodium azide using1-dodecylquinolin-1-ium bis(trifluoromethane)sulfonimide ([DDQM][TFSI]) in dimethyl sulfoxide under microwave irradiation (Scheme 61). 138 All the triazoles were obtained in good to high yields (65%–94%) within 2 min. As shown in Scheme 62, the plausible mechanism involved the initial formation of nitrostyrene from the reaction of aldehyde derivatives with nitroalkanes, which, in addition to the azide to the CC bond, formed an intermediate (I).…”