A method has been developed for direct counting of noble gas atoms and has been demonstrated for selected isotopes of krypton. In principle, a few atoms of the noble gases argon, krypton, xenon and radon can now be counted with isotopic selectivity whether stable or radioactive. A concept was originated in which a laser method would be used to count noble gas atoms of a particular isotope that are moving freely in an enclosure. As the concept developed, a parallel with Maxwell's sorting demon became quite obvious since our plan was to sort out only atoms of a given type (2 selection), e.g. krypton atoms, from any other atom in the enclosure and then to sort the atom by isotope ( A selection) before removing the atom from the gas compartment. The plan was to count each atom as it was stored in a target until all atoms were counted. Thus, our realisation of Maxwell's demon can remember each atom as it is counted until all of them have been sorted out from background atoms. Development of several special components was required to carry out these objectives.Resonance ionisation spectroscopy ( RIS) is quantum-state selective, yet an efficient method for the ionisation of free atoms. However, to accomplish this Z-selective ionisation for the noble gases requires lasers in the far vacuum ultraviolet (vuv) region. Extensive theoretical work was done to guide experiments for vuv generation with lasers. This was especially important for generating 116.5 nm radiation for the first excitation step in the RIS of krypton. The laser experiments themselves led to the development of a laser system, driven by a Nd : YAG pump, that could produce the necessary 116.5 nm radiation at a 10 Hz rate with about 500 nJ per pulse. It should be somewhat easier to produce the radiation needed for RIS of argon. Very effective schemes for xenon have already been demonstrated.In spite of the considerable advances made for vuv generation using lasers, the effective volume for ionisation of krypton in a single laser pulse remained below 10-3cm3. Thus, nearly lo7 laser pulses would be required to find all of the atoms