In order to examine the seawater--seafloor sediment interactions that influence the 9 chemical composition of seawater through time, we examined hundreds of pore fluid 10 geochemical analyses from 13 clay--rich sedimentary successions drilled by the ODP--11 IODP. Chemical trends such as monotonous increases in Ca 2+ , and decreases in Mg 2+ and 12 δ 18 O with depth are traditionally interpreted to result from water--rock interaction. In 13 this view, the release of Ca 2+ into fluids and the uptake of Mg 2+ and 18 O mainly results 14 from the formation of low--temperature clays in the sediment and within underlying 15 basalts. Chloride concentration profiles and isotopic compositions, however, suggest 16 that different processes may influence pore water geochemistry. The data examined 17 here show relatively constant chloride contents but with a systematic decrease in δ 37 Cl 18 of chlorides with depth from 0 permil (the seawater value) down to --8.5 permil. The 19 δ 37 Cl data are highly correlated with δ 18 O (with δ 18 O down to --5.7 permil). 20 further experimental work on both chlorine and oxygen isotopes is certainly needed, the 45 results of this study indicate that ion--filtration should be considered as a potential 46 mechanism for fractionating isotopic species in sediment pore waters, particularly for 47 oxygen isotope ratios whose variations are often commonly attributed to water--rock 48 exchange. 49 I) Introduction 50 Water--rock interactions and transport of solutes by water are means by which 51 chemical elements are redistributed at the surface of the Earth. Through these processes, 52 the Earth's surface and subsurface reservoirs, such as seawater, continental crust, 53 sediments, altered oceanic crust, were created, maintained and modified all along the 54 Earth's history. To decipher this history, geochemical tools were developed. They 55 include stable isotope geochemistry of traditional elements (O, H, C, N, S) and non--56 traditional elements (e.g., Cl, Li, B, Cu, U, Zn, Se). Although chlorine stable isotope 57 geochemistry started in the early times of the stable isotope geochemistry, it remains an 58 under--utilized tool. Yet, chlorine stable isotopes ( 37 Cl & 35 Cl) of dissolved chlorides are 59 proved to be powerful tools to describe transport mechanism of fluids. Physical 60 processes mainly fractionate them during fluid transports in geological media: diffusion 61 (