Darstellung und reaktionen von 1,3-bis-trimethylsilyloxy-isobenzofuranen und -isoindolen

Troll, T.; Ollmann, Georg W.

doi:10.1016/s0040-4039(01)81941-9

Cited by 24 publications

(4 citation statements)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…de Luca and colleagues used cyclic voltammetry with a glassy carbon cathode in dimethylformamide to examine the electrochemical behaviors of tetrabromo- and tetrachlorophthalic anhydride. Troll and Ollmann reduced brominated and chlorinated derivatives of phthalic anhydrides, along with phthalic imides, to electrosynthesize some 1,3-bis(trimethyl)silyloxy-substituted isobenzofurans and isoindoles. The electrochemical reduction of halogenated esters of fumaric acid was investigated by Goulart and colleagues at mercury and carbon cathodes in dimethylformamide and in acetonitrile/water mixtures.…”

Section: Halogenated Environmental Pollutantsmentioning

confidence: 99%

Electroreductive Remediation of Halogenated Environmental Pollutants

et al. 2016

View full text Add to dashboard Cite

Electrochemical reduction of halogenated organic compounds is gaining increasing attention as a strategy for the remediation of environmental pollutants. We begin this review by discussing key components (cells, electrodes, solvents, and electrolytes) in the design of a procedure for degrading a targeted pollutant, and we describe and contrast some experimental techniques used to explore and characterize the electrochemical behavior of that pollutant. Then, we describe how to probe various mechanistic features of the pertinent electrochemistry (including stepwise versus concerted carbon-halogen bond cleavage, identification of reaction intermediates, and elucidation of mechanisms). Knowing this information is vital to the successful development of a remediation procedure. Next, we outline techniques, instrumentation, and cell designs involved in scaling up a benchtop experiment to an industrial-scale system. Finally, the last and major part of this review is directed toward surveying electrochemical studies of various categories of halogenated pollutants (chlorofluorocarbons; disinfection byproducts; pesticides, fungicides, and bactericides; and flame retardants) and looking forward to future developments.

show abstract

Section: Halogenated Environmental Pollutantsmentioning

confidence: 99%

Electroreductive Remediation of Halogenated Environmental Pollutants

et al. 2016

View full text Add to dashboard Cite

show abstract

“…Isoindoles are promising active biological materials 1,2 with interesting spectral properties and are the subject of study for important theoretical questions, such as: aromaticity, tautomerism [3][4][5][6][7][8] and represent the important source of the reactive compounds and synthons used for cycloaddition reactions, [9][10][11][12][13][14] the study of the organic reactions mechanisms, new rearrangements [15][16][17][18][19][20][21] and the creation of new colouring agents. [22][23][24] The most typical reaction for simple isoindole systems is the Diels-Alder reaction but previously this reaction was associated only with isoindoles prevalently in the isoindole tautomeric form.…”

Section: Introductionmentioning

confidence: 99%

The Curtin–Hammett principle in action: 1-amino-3H-isoindole in cycloaddition reactions

Levkov¹,

Turov²,

Шишкин³

et al. 2010

Tetrahedron

View full text Add to dashboard Cite

“…Diels-Alder adducts derived from fused azino-and azoloisoindoles with maleimides undergo further rearrangements and form compounds with addends in both a 1:1 and 1:2 ratio, that possess intriguing properties. [9][10][11][12] Reaction of 2,4-dimethylpyrimido[2,1-a]isoindole with a variety of maleimides gives derivatives of 4-aminobenzo[f] isoindole which exhibit notably strong fluorescence. 12 In the current research, we developed a new synthetic route to the latter compounds, giving better yields and easier to implement than the existing one.…”

mentioning

confidence: 99%

Synthesis and Fluorescence Properties of 4-aminobenzo[f]Isoindole Derivatives

Levkov

Voitenko

Zaporozhets

et al. 2011

Journal of Chemical Research

View full text Add to dashboard Cite

We report a new route to benzo[f ]isoindole derivatives that possess strong fluorescence. The structure of the newly synthesised compounds was confirmed by NMR, IR and mass spectra, along with X-ray crystallographic studies. Absorption and fluorescence spectra of the new compounds were recorded. It was established that tautomerism of 4-aminobenzo[f ]isoindoles defines the properties of these compounds. Also, the influence of substituents at the N-2 position on the luminescence properties was studied; the fluorescence intensity is dependent on the water content in organic solvents, and can be used to indicate their moisture content.

show abstract

Darstellung und reaktionen von 1,3-bis-trimethylsilyloxy-isobenzofuranen und -isoindolen

Cited by 24 publications

References 6 publications

Electroreductive Remediation of Halogenated Environmental Pollutants

Electroreductive Remediation of Halogenated Environmental Pollutants

The Curtin–Hammett principle in action: 1-amino-3H-isoindole in cycloaddition reactions

Synthesis and Fluorescence Properties of 4-aminobenzo[f]Isoindole Derivatives

Contact Info

Product

Resources

About