Darstellung einiger Salze des Schwefeloxiddifluoridimids und deren Reaktion mit Dimethylzinndihalogeniden / Preparation and Properties of Some Sulfuroxidedifluorideimide Salts and their Reaction with Dimethyltindihalides

Feser, Manfred; Höfer, Rainer; Glemser, Oskar

doi:10.1515/znb-1974-11-1204

Cited by 11 publications

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“…A considerable number of covalently bonded main-group derivatives of the F 2 OSN- ligand are known as exemplified by XNSOF 2 (X = H, F, Cl, Br, I, (CH 3 ) 3 Si, CH 3 OS(O), CF 3 CO, CF 3 S, OCNSO 2 , Cl 3 PNSO 2 , OCNCO, (C 6 H 5 ) 4 As, (C 6 H 5 ) 4 P, OPF 2 , OPFCl, OPCl 2 , SPCl 2 , (CH 3 ) 2 SnCl, (CH 3 ) 2 SnBr), − X(NSOF 2 ) 2 (X = (CH 3 ) 2 Si, (C 6 H 5 )CH 3 Si, OS, OSe, O 2 S, OPF, OPCl, SPCl, SPF, (CH 3 ) 2 Sn), − X(NSOF 2 ) 3 (X = B, P, As, Sb, CH 3 Si, OP, SP), − (NCNSOF 2 ) 3 , [B(NSOF 2 ) 4 ] − , Si(NSOF 2 ) 4 , and Sb(NSOF 2 ) 5 . , Examples of transition metal derivatives include Hg(NSOF 2 ) 2 , AgNSOF 2 , Re(CO) 5 (NSOF 2 ), [(CO) 4 M(NSOF 2 )] 2 (M = Re, Mn − ), M(NSOF 2 ) 2 (M = Ni, Co, Cu), Cu(NSOF 2 )(AsF 5 NSOF 2 ), [Ni(SO 2 ) 2 ][AsF 4 (NSOF 2 )] 2 , as well as the [Ag(NSOF 2 ) 2 ] − and [M(NSOF 2 ) 4 ] 2– anions (M = Zn, Hg, Mn, Co, Pd, Cu). , Their structural characterizations have been limited to IR and/or Raman spectroscopy, NMR spectroscopy, electron diffraction, and mass spectrometry. The only F 2 OSN- derivatives that have been characterized by single-crystal X-ray diffraction are (NCNSOF 2 ) 3 , [Ni(SO 2 ) 2 ][AsF 4 (NSOF 2 ) 2 ] 2 , and [(CO) 4 Mn(NSOF 2 )] 2 . , In the case of (NCNSOF 2 ) 3 , the trimeric structure is comprised of an s -C 3 N 3 ring in which the F 2 OSN- groups are bonded to carbon .…”

Section: Introductionmentioning

confidence: 99%

Thiazyl Trifluoride (NSF₃) Adducts and Imidodifluorosulfate (F₂OSN-) Derivatives of Hg(OTeF₅)₂

2015

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Reactions of Hg(OTeF5)2 with excess amounts of NSF3 at 0 °C result in the formation of NSF3 adducts having the compositions [Hg(OTeF5)2·N≡SF3]∞ (1), [Hg(OTeF5)2·2N≡SF3]2 (2), and Hg3(OTeF5)6·4N≡SF3 (3). When the reactions are carried out at room temperature, oxygen/fluorine metatheses occur yielding the F2OSN- derivatives [Hg(OTeF5)(N═SOF2)·N≡SF3]∞ (4) and [Hg3(OTeF5)5(N═SOF2)·2N≡SF3]2 (5). The proposed reaction pathway leading to F2OSN- group formation occurs by nucleophilic attack by a F5TeO- group at the sulfur(VI) atom of NSF3, followed by TeF6 elimination. Tellurium hexafluoride formation was confirmed by (19)F NMR spectroscopy. The NSF3 molecules are terminally N-coordinated to mercury, whereas the F2OSN- ligands are N-bridged to two mercury atoms. The compound series was characterized by low-temperature single-crystal X-ray diffraction and low-temperature Raman spectroscopy. Several structural motifs are observed within this structurally diverse series. These include the infinite chain structures of the related compounds, 1 and 4; 2, a dimeric structure which possesses an (HgO(μ))2 ring at its core; 3, a structure based on a cage comprised of a (HgO(μ))3 ring that is capped on each face by μ(3)-oxygen bridged F5TeO- groups; and 5, a dimeric structure possessing two distorted (Hg3O2N) rings that are formally derived from 3 by replacement of a F5TeO- group by a F2OSN- group in each ring. Quantum-chemical calculations were carried out to gain insight into the bonding of the μ(3)-oxygen bridged teflate groups observed in structure 3. Compounds 1-5 represent a novel class of neutral transition metal complexes with NSF3, providing the first examples of NSF3 coordination to mercury. Compounds 4 and 5 also provide the only examples of F2OSN- derivatives of mercury that have been characterized by single-crystal X-ray diffraction.

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Section: Introductionmentioning

confidence: 99%

Thiazyl Trifluoride (NSF₃) Adducts and Imidodifluorosulfate (F₂OSN-) Derivatives of Hg(OTeF₅)₂

2015

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“…Bei der Umsetzung von Ag(NS0F2) (1) [6] mit Tetraphenylarsoniumdifluorooxoschwefelimidat (2) [7] in wasserfreiem Methanol entsteht mit 60-proz. Ausbeute Tetraphenylarsonium-bis-difluorooxoschwefelimidato-argentat (3), das nach Umkristallisation aus methanolischer Lösung im Dunkeln in farblosen Kristallen anfällt.…”

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Difluorooxoschwefelimidato-metallate, [Ag(NSOF₂)₂]- und [M(NSOF₂)₄ ^2-, (M = Cu, Zn, Mn) / Difluorooxosulfurimidato-metallates, [Ag(NSOF2)2]- and [M(NSOF2)4]2- (M = Cu, Zn, Mn)

Eisenbarth

Sundermeyer

1981

Zeitschrift Für Naturforschung B

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Chemie des Thiazylfluorids (NSF) und Thiazyltrifluorids (NSF3): Ein Vierteljahrhundert Schwefel-Stickstoff-Fluor-Chemie

Glemser

Mews

1980

Angew. Chem.

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und Rudiger Mews"' %urn Gedenken an Hans uon Wartenberg anlaRlich seines 100. Geburtstaged'] Seit die ersten Schwefel-Stickstoff-Fluor-Verbindungen vor 25 Jahren synthetisiert wurden1'1, sind beim Studium dieser Spezies rnit kovalent gebundenem Fluor groRe Fortschritte erzielt worden[, ' I. Zwei kleine Molekule -Thiazylfluorid (NSF) und Thiazyltrifluorid (NSF,) ~ sind Schliisselsubstanzen des Gebiets: Fast alle Schwefel-Stickstoff-Fluor-Verbindungen lassen sich von ihnen ableiten.F Eine bemerkenswerte Umsetzung der NSF-Vorstufe Hg(NSF2)2 [vgl. Reaktion ( 2 ) ] rnit (CF3)2CN2 laBt sich im 904 0 Verlag Chemie. GmbH, 0-6940 Weinheim, 1980 0044-8249/80/11I1-0904 8 02.50/0 Angew. Chem. 92. 904-921 (1980)Angew. Chem. 92, 904-921 (1980) Angew. Chem. 92, 921-929 (1980)

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Darstellung einiger Salze des Schwefeloxiddifluoridimids und deren Reaktion mit Dimethylzinndihalogeniden / Preparation and Properties of Some Sulfuroxidedifluorideimide Salts and their Reaction with Dimethyltindihalides

Abstract: M a n f r e d F e s e r , R a i n e r H ö f e r u n d O s k a r G le m s e r Anorganisch-Chemisches Institut der Universität Göttingen (Z. N aturforsch. 29b, 716-718 [1974]

Cited by 11 publications

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Thiazyl Trifluoride (NSF₃) Adducts and Imidodifluorosulfate (F₂OSN-) Derivatives of Hg(OTeF₅)₂

Thiazyl Trifluoride (NSF₃) Adducts and Imidodifluorosulfate (F₂OSN-) Derivatives of Hg(OTeF₅)₂

Difluorooxoschwefelimidato-metallate, [Ag(NSOF₂)₂]- und [M(NSOF₂)₄ ^2-, (M = Cu, Zn, Mn) / Difluorooxosulfurimidato-metallates, [Ag(NSOF2)2]- and [M(NSOF2)4]2- (M = Cu, Zn, Mn)

Chemie des Thiazylfluorids (NSF) und Thiazyltrifluorids (NSF3): Ein Vierteljahrhundert Schwefel-Stickstoff-Fluor-Chemie

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Darstellung einiger Salze des Schwefeloxiddifluoridimids und deren Reaktion mit Dimethylzinndihalogeniden / Preparation and Properties of Some Sulfuroxidedifluorideimide Salts and their Reaction with Dimethyltindihalides

Abstract: M a n f r e d F e s e r , R a i n e r H ö f e r u n d O s k a r G le m s e r Anorganisch-Chemisches Institut der Universität Göttingen (Z. N aturforsch. 29b, 716-718 [1974]

Cited by 11 publications

References 0 publications

Thiazyl Trifluoride (NSF3) Adducts and Imidodifluorosulfate (F2OSN-) Derivatives of Hg(OTeF5)2

Thiazyl Trifluoride (NSF3) Adducts and Imidodifluorosulfate (F2OSN-) Derivatives of Hg(OTeF5)2

Difluorooxoschwefelimidato-metallate, [Ag(NSOF2)2]- und [M(NSOF2)4 2-, (M = Cu, Zn, Mn) / Difluorooxosulfurimidato-metallates, [Ag(NSOF2)2]- and [M(NSOF2)4]2- (M = Cu, Zn, Mn)

Chemie des Thiazylfluorids (NSF) und Thiazyltrifluorids (NSF3): Ein Vierteljahrhundert Schwefel-Stickstoff-Fluor-Chemie

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Thiazyl Trifluoride (NSF₃) Adducts and Imidodifluorosulfate (F₂OSN-) Derivatives of Hg(OTeF₅)₂

Thiazyl Trifluoride (NSF₃) Adducts and Imidodifluorosulfate (F₂OSN-) Derivatives of Hg(OTeF₅)₂

Difluorooxoschwefelimidato-metallate, [Ag(NSOF₂)₂]- und [M(NSOF₂)₄ ^2-, (M = Cu, Zn, Mn) / Difluorooxosulfurimidato-metallates, [Ag(NSOF2)2]- and [M(NSOF2)4]2- (M = Cu, Zn, Mn)