With the aid of a technique that induces electric
field-generated capillary waves on polymeric
liquid surfaces and the resulting wave propagation characteristics
detected by an optical diffraction
method, we examined the surface tension and steady shear viscosity of
low molecular weight poly(dimethylsiloxane) (PDMS) and poly(ethylene glycol) (PEG) at
different temperatures. The surface tension
values are in quite good agreement with those reported in the
literature, whereas the shear viscosity
values are not as accurate, though they agree within 7% with those
determined by a capillary viscometer.
The temperature dependences of the surface tensions of both are in
agreement with the literature. On
the other hand, they differ in their molecular weight dependences,
though PDMS shows a small difference
due to its relatively small molecular weight, but the PEG slope was in
good agreement in spite of its low
molecular weight due to its hydrogen bonding. PDMS and PEG show
different mode behaviors at high
frequency and low temperature because of the overdamped mode appearance
for PEG.