We suggest to study the production mechanism and some details of the production properties to probe the structure of the DDπ resonance T + cc recently observed by the LHCb Collaboration.If the resonance is produced as a four-quark state, one can find the corresponding finger prints via measurements on some production properties that are the same as those of Ξ cc . On the other hand, if T + cc is produced as a hadron molecule, the measurement on the momentum correlation of DD * can be a smoking gun to make the judgement.