2019
DOI: 10.3390/cryst9050245
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Czochralski Growth, Magnetic Properties and Faraday Characteristics of CeAlO3 Crystals

Abstract: CeAlO3 crystals were grown in different growth atmospheres by the Czochralski method. The lattice parameters and space group of CeAlO3 crystal were determined by Rietveld structure refinement of X-ray diffraction (XRD) data. The influence of Ce4+ ions in the crystal on the transmittance and crystal color was confirmed by XPS analysis. Magnetization curve at room temperature and temperature dependencies of the magnetic susceptibility in two different directions were measured, indicating that CeAlO3 crystal has … Show more

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Cited by 16 publications
(12 citation statements)
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“…[46]. The CeAlO 3 material [151] is also transparent up to ∼2500 nm and its Verdet constant is about twice as high as the one of CeF 3 at the 633 and 1064 nm wavelengths. Apart from these cerium-based materials, Verdet constant investigations of (Dy X Y 0.95−X La 0.05 ) 2 O 3 (with variable doping X = 0.7, 0.8 and 0.9) ceramics [129,130], EuF 2 crystal [42,159] and Dy 2 O 3 ceramics [48] were recently reported.…”
Section: Nir-mir Region (λ > 1100 Nm)mentioning
confidence: 97%
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“…[46]. The CeAlO 3 material [151] is also transparent up to ∼2500 nm and its Verdet constant is about twice as high as the one of CeF 3 at the 633 and 1064 nm wavelengths. Apart from these cerium-based materials, Verdet constant investigations of (Dy X Y 0.95−X La 0.05 ) 2 O 3 (with variable doping X = 0.7, 0.8 and 0.9) ceramics [129,130], EuF 2 crystal [42,159] and Dy 2 O 3 ceramics [48] were recently reported.…”
Section: Nir-mir Region (λ > 1100 Nm)mentioning
confidence: 97%
“…There are many more reports on promising magneto-active materials for the VIS-NIR region, which offer properties superior to the TGG crystal, most of them targeting on the enhancement of the Verdet constant. From the vast number of these materials, we may mention, e.g., NaTb(WO 4 ) 2 [136], TSLAG [81,137], Na 2 Tb 4 (MoO 4 ) 7 [138], LiCaTb 5 (BO 3 ) 6 [139], RE:TGG (RE= Ce [140], Pr [141], Ho [142], Tm [143] or Dy [144]), TbVO 4 [145], Nd:TbVO 4 [146], Na 2 Ce(MoO 4 ) 2 [147], TCZ [148,149], Tb 2 Hf 2 O 7 [150] or CeAlO 3 [151]. Table 2.…”
Section: Vis-nir Region (400 < λ < 1100 Nm)mentioning
confidence: 99%
“…Much more data about the Verdet constant can be found in the literature (or calculated from presented data) [ 43 , 125 , 159 , 161 , 162 , 163 , 164 , 165 , 166 , 167 , 168 , 169 , 170 , 171 , 172 , 173 , 174 , 175 , 176 , 177 , 178 , 179 , 180 , 181 ], but the value is usually given for a single wavelength and other figures of merit are often missing. Differences in reported data are understandable because of the high sensitivity of the parameters-to-dopants concentration.…”
Section: Choice Of the Faraday Materialsmentioning
confidence: 99%
“…As important representatives of photoelectric functional materials, the supplement of synthetic crystals increases continuously, and the improvement on the functions and qualities of the crystals are required [1,2]. Among the crystal growth methods, the Czochralski (Cz) technique is one of the most important methods employed for crystal production [3,4]. In the process of crystal growth by the Czochralski method, the temperature and concentration gradients induce the heat and mass transfer, and drive the diffusion and natural convections (including the thermo-solutal-capillary convection and capillary-buoyancy convections).…”
Section: Introductionmentioning
confidence: 99%