Cyclopolymerization of conformationally controlled unsymmetrical dienes: 2‐(o‐vinylphenoxy)ethyl methacrylate and acrylate

Chu, Shaw‐Chang; Butler, George B.

doi:10.1002/pol.1977.130150504

Cited by 6 publications

(1 citation statement)

References 7 publications

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“…Since the initial investigation by Butler and Bunch, 42 these cyclopolymerizations have been the subject of much interest. [43][44][45][46][47][48][49] Radical initiation has been the most widely employed method of promoting cyclopolymerization and the mechanism has been studied extensively. [50][51][52][53] Initially, cyclopolymers formed from radicalinitiated polymerization of 1,6-dienes were assigned structures based upon a linear network of six-membered rings linked by methylene units.…”

Section: Development Of Cyclopolymerizationmentioning

confidence: 99%

Non-cross-linked and cross-linked poly(alkylmethyldiallylammonium halides): synthesis and aggregation behavior

Wang

Engberts²

1998

J. Phys. Org. Chem.

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Hydrophobically modified polyelectrolytes (polysoaps) are a unique class of water-soluble polymers containing distinct hydrophobic and hydrophilic regions. Above a certain concentration, polysoaps form intramolecular and intermolecular aggregates in aqueous solution. They have attracted much attention not only for their ability to mimic some functions demonstrated by biopolymers but also for their important industrial applications. This review highlights some interesting features of novel non-cross-linked and cross-linked poly(alkylmethyldiallylammonium halides) that have been described in recent years.

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Section: Development Of Cyclopolymerizationmentioning

confidence: 99%

Non-cross-linked and cross-linked poly(alkylmethyldiallylammonium halides): synthesis and aggregation behavior

Wang

Engberts²

1998

J. Phys. Org. Chem.

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Synthesis of syndiotactic poly(methacrylic acid) by free‐radical polymerization of the pseudo‐divinyl monomer formed with methacrylic acid and catechol

Saito

2012

J of Applied Polymer Sci

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Syndiotactic poly(methacrylic acid) (Syn‐PMAA, r diad = 91 mol %) was synthesized by free radical polymerization of methacrylic acid (MAA) with catechol. The pseudo‐divinyl monomer was formed with one catechol and two MAA molecules by the hydrogen bonding between OH groups of catechol and COOH group of MAA. When the free radical polymerization of the pseudo‐divinyl monomer was carried out, intra‐ and intermolecular addition proceeded with racemic addition. The hydrogen bonding was the driving force to control tacticity. We discussed the effects of solvent, temperature, and the concentrations of MAA and catechol on the pseudo‐divinyl monomer formation. The highly syndiotactic PMAA was successfully obtained. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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Cyclopolymerization of divinyloxy monomers by iodine

Seung

Young

1978

J. Polym. Sci. B Polym. Lett. Ed.

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Cyclopolymerization of conformationally controlled unsymmetrical dienes: 2‐(o‐vinylphenoxy)ethyl methacrylate and acrylate

Cited by 6 publications

References 7 publications

Non-cross-linked and cross-linked poly(alkylmethyldiallylammonium halides): synthesis and aggregation behavior

Non-cross-linked and cross-linked poly(alkylmethyldiallylammonium halides): synthesis and aggregation behavior

Synthesis of syndiotactic poly(methacrylic acid) by free‐radical polymerization of the pseudo‐divinyl monomer formed with methacrylic acid and catechol

Cyclopolymerization of divinyloxy monomers by iodine

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