1971
DOI: 10.1021/jo00805a027
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Cyclization of cis- and trans-2-(2-methoxycyclohexyl)ethanol to cis- and trans-perhydrobenzofurans

Abstract: We have reported2 that compounds of type 1 undergo cyclization with tosyl chloride-pyridine to form perhydrobenzofurans 2, with loss of a methoxyl group. This reaction, which we first observed in degradations of the antibiotic fumagillin,3 involves a methoxonium ion intermediate.4

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Cited by 9 publications
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