Cyanide Thermodynamics. 1. Stability Constants of Cadmium(ii) and Zinc(ii) Cyanide Complexes in Aqueous Acetonitrile Mixtures

Kurnia, Kiki A.; Giles, Dion E.; May, Peter M.; Singh, Pritam; Hefter, Glenn

doi:10.1080/00958979608022704

Cited by 3 publications

References 18 publications

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Electrochemistry of Cadmium

Stroka

Maksymiuk

Galus

2006

Encyclopedia of Electrochemistry

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The sections in this article are Double‐layer Properties of Cadmium Electrodes Electrochemical Properties and Kinetics of the Cd ( II )/ Cd ( Hg ) Systems Electrochemistry in Aqueous Solutions Kinetics of Simple Ions Influence of a Catalyst Influence of Inhibitors Electrochemistry in Mixed and Nonaqueous Solvents Electrochemical Properties of the Cadmium Complexes Determination of Stability Constants Electrochemical Preparation of Cadmium Complexes Preparation and Electrochemical Properties of Cadmium Chalcogenides CdS CdSe Cd Te Properties of Cadmium Intermetallic Compounds Cadmium Underpotential Deposition and Electrodeposition on Solid Electrodes Deposition of Cd on Cadmium Electrode Electrodeposition of Cd on Other Solid Substrates Gold Platinum Silver Copper Silicon Other Substrates Passivation and Corrosion of Cadmium Passivation of Cadmium Electrode Corrosion of Cadmium Applied Electrochemistry Batteries Cadmium–Mercuric Oxide Primary Cells Cadmium–Nickel Oxide ( Ni – Cd ) Secondary Cells Cadmium–Silver Oxide Secondary Cells Application in Electrochemical Sensors Potentiometric Sensors Amperometric‐voltammetric Sensors

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Electrochemistry of Cadmium

Stroka

Maksymiuk

Galus

2006

Encyclopedia of Electrochemistry

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Cyanide thermodynamics 2. Stability constants of copper(I) cyanide complexes in aqueous acetonitrile mixtures

Kurnia

Giles

May

et al. 1996

Talanta

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Acetonitrile cluster solvation in a cryogenic ethane-methane-propane liquid: Implications for Titan lake chemistry

Corrales

Trumbo

et al. 2017

The Journal of Chemical Physics

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The atmosphere of Titan, Saturn's largest moon, exhibits interesting UV-and radiation-driven chemistry between nitrogen and methane, resulting in dipolar, nitrile-containing molecules. The assembly and subsequent solvation of such molecules in the alkane lakes and seas found on the moon's surface are of particular interest for investigating the possibility of prebiotic chemistry in Titan's hydrophobic seas. Here we characterize the solvation of acetonitrile, a product of Titan's atmospheric radiation chemistry tentatively detected on Titan's surface [H. B. Niemann et al., Nature 438, 779-784 (2005)], in an alkane mixture estimated to match a postulated composition of the smaller lakes during cycles of active drying and rewetting. Molecular dynamics simulations are employed to determine the potential of mean force of acetonitrile (CH 3 CN) clusters moving from the alkane vapor into the bulk liquid. We find that the clusters prefer the alkane liquid to the vapor and do not dissociate in the bulk liquid. This opens up the possibility that acetonitrile-based microscopic polar chemistry may be possible in the otherwise nonpolar Titan lakes.

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Cyanide Thermodynamics. 1. Stability Constants of Cadmium(ii) and Zinc(ii) Cyanide Complexes in Aqueous Acetonitrile Mixtures

Cited by 3 publications

References 18 publications

Electrochemistry of Cadmium

Electrochemistry of Cadmium

Cyanide thermodynamics 2. Stability constants of copper(I) cyanide complexes in aqueous acetonitrile mixtures

Acetonitrile cluster solvation in a cryogenic ethane-methane-propane liquid: Implications for Titan lake chemistry

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