2021
DOI: 10.26434/chemrxiv-2021-n949l
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Cy-clo-tetrakis(μ-diphenylphosphido)-1,5-bis(tri-tert-butylphosphine-tetracopper(I)

Steven G. Dannenberg
1
,
Rory Waterman
2

Abstract: Copper phosphido cluster Cu4(μ-PPh2)4(PtBu3)2 was synthesized by three synthetic methods and structurally characterized by X-ray diffraction and 1H, 31P, 13C and 31P HMBC NMR spectroscopy. Cu4(μ-PPh2)4(PtBu3)2 was also demonstrated to be a hydrophosphination pre-catalyst.

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