Customizing ultraviolet curable polymer‐ink properties via reactive diluent modification and viscosity control

Abstract

In inkjet 3D printing, material selection plays a crucial role in shaping both printing performance and material characteristics. Achieving the desired properties relies on precisely formulated compositions. In this context, ultraviolet (UV) curable polymers require specific viscosities, typically ranging from 3700 to 5700 mPa·s, to function effectively in 3D printing's material jetting technique, preventing complications during material dispensing. This study formulates UV‐curable polymers by blending four distinct monomers: Genomer 4247 Aliphatic Urethane Dimethacrylate, 1,10‐Decanediol Dimethacrylate, Isobornyl Acrylate, and Methyl Acrylate, within a controlled dark room environment at room temperature to prevent undesired crosslinking reactions during mixing. The selection of these monomers and their compositions is meticulous, considering their capacity to achieve specified viscosities and enhance overall material performance. This formulation process yields a wide range of UV‐curable polymer viscosities. The study employs comprehensive methodologies, including rheometry, Fourier transform infrared analysis, Soxhlet extraction, thermal analysis, and tensile testing, for rigorous evaluation of viscosity, curing efficiency, thermal characteristics, and mechanical performance. Notably, mechanical and chemical performance exhibits marginal differences within the viscosity range, attributed to UV‐curable polymer crosslinking, consistently exceeding 99% for all samples. However, the polymer composed of 98% v/v oligomer and methyl acrylate (MA) demonstrates notably better thermal and mechanical properties due to its 99.91% gel content crosslinking. Remarkable polymer fabrication thus occurs within the desired viscosity range.