Current Trends in the Synthesis of Inorganic and Organoelement Phosphorus- And Sulfur-Containing Polymers. A Review

Abstract

The analysis of the literature data on the set of reactions for the production of macromolecules with a high content of phosphorus and sulfur is carried out, and the main approaches allowing to involve these elements in the composition of polymers and polymer materials, considering the fundamental principles of green chemistry, are considered. The methods leading to the formation of functional polymers under mild conditions with minimal energy consumption from external sources necessary for the synthesis, which can become new growth points of green industrial technologies, are considered. Particular attention is paid to the issues of synthesis of polyphosphazenes and polyphosphoesters for biomedical purposes, as well as the inverse vulcanization reaction with the formation of polymers that are used in sorption wastewater treatment, the creation of current sources and IR optics.