A new series of sulfobetaine surfactants with doubleâchain singleâhead structure were derived from 1,3âdialkyl glyceryl ethers and their performances in reducing Daqing crude oil/connate water interfacial tension (IFT) in the absence of alkali were studied. With a large hydrophilic head group and double hydrophobic chains, these surfactants are efficient at reducing crude oil/connate water IFT. Those with didecyl and dioctyl are good hydrophobic surfactants that can reduce Daqing crude oil/connate water to ultraâlow IFT by mixing with a small molar fraction of various conventional singleâchain hydrophilic surfactants, such as αâolefin sulfonates, dodecyl polyoxyethylene (10) ether, and cetyl dimethyl hydroxypropyl sulfobetaine. The asymmetric doubleâchain sulfobetaine derived from 1âdecylâ3âhexyl glyceryl ether can reduce Daqing crude oil/connate water IFT to ultraâlow solely over a wide concentration range (0.03â10âmM or 0.0017â0.58âwt.%), which allows for use of an individual surfactant instead of mixed surfactants to avoid chromatographic separation in the reservoir. In addition, formulations rich in sulfobetaine surfactants show low adsorption on sandstone, keeping the negatively charged solid surface waterâwet, and forming crude oilâinâwater emulsions. These new sulfobetaine surfactants are, therefore, good candidates for surfactantâpolymer flooding free of alkali.