Current advances and applications of in-tube solid-phase microextraction

Queiroz, Maria Eugênia Costa; Souza, Israel Donizéti de; Marchioni, Camila

doi:10.1016/j.trac.2018.12.018

Cited by 113 publications

(50 citation statements)

References 53 publications

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“…Out of this first design, different SPME configurations have been developed progressively to improve this technique [41]. This includes mainly the following SPME modes: on-fiber solid-phase microextraction (f-SPME) [42], arrow fiber solid-phase microextraction (af-SPME) [43], in-tube solid-phase microextraction (it-SPME) [44], thin-film solid-phase microextraction (tf-SPME) [45], and stir-based solid-phase microextraction, including stir-bar (sb-SPME) [46] and stir-cake solid-phase microextraction (sc-SPME). The introduction of MOFs as sorbent materials in the different SPME devices and configurations has been gradual.…”

Section: Metal-organic Framework In Analytical Separationsmentioning

confidence: 99%

“…The development of other capillary modes shifts to the incorporation of novel materials and the improvement of the technique. Other capillary modes include sorbent-packed, fiber-packed, and monolithic phases [44,121,122]. Figure 6A compiles a representation of the main four it-SPME capillary configurations.…”

Section: Mofs In In-tube Solid-phase Microextraction (It-spme)mentioning

confidence: 99%

“…The sample is injected, flows through the device, and goes back to the sample vial through the device again completing a cycle. In this modality, it is important not only to optimize the sample flow, but also the number of required cycles to obtain the maximum extraction efficiency [44,122]. Figure 6B shows a schematic representation of both configurations.…”

Section: Mofs In In-tube Solid-phase Microextraction (It-spme)mentioning

confidence: 99%

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Metal–Organic Frameworks as Key Materials for Solid-Phase Microextraction Devices—A Review

et al. 2019

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Metal–organic frameworks (MOFs) have attracted recently considerable attention in analytical sample preparation, particularly when used as novel sorbent materials in solid-phase microextraction (SPME). MOFs are highly ordered porous crystalline structures, full of cavities. They are formed by inorganic centers (metal ion atoms or metal clusters) and organic linkers connected by covalent coordination bonds. Depending on the ratio of such precursors and the synthetic conditions, the characteristics of the resulting MOF vary significantly, thus drifting into a countless number of interesting materials with unique properties. Among astonishing features of MOFs, their high chemical and thermal stability, easy tuneability, simple synthesis, and impressive surface area (which is the highest known), are the most attractive characteristics that makes them outstanding materials in SPME. This review offers an overview on the current state of the use of MOFs in different SPME configurations, in all cases covering extraction devices coated with (or incorporating) MOFs, with particular emphases in their preparation.

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Section: Metal-organic Framework In Analytical Separationsmentioning

confidence: 99%

Section: Mofs In In-tube Solid-phase Microextraction (It-spme)mentioning

confidence: 99%

Section: Mofs In In-tube Solid-phase Microextraction (It-spme)mentioning

confidence: 99%

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Metal–Organic Frameworks as Key Materials for Solid-Phase Microextraction Devices—A Review

et al. 2019

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“…Several review articles have been published in recent years on SPME, highlighting various application areas, developments, and materials/coatings [7,11,[16][17][18][19][20][21][22][23][24][25][26][27][28][29]. Recently, a review article has been published as an overview of the most cited review articles on SPME covering theory, applications, automation, and future trends [30].…”

Section: Introductionmentioning

confidence: 99%

Bioanalytical HPLC Applications of In-Tube Solid Phase Microextraction: A Two-Decade Overview

2020

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In-tube solid phase microextraction is a cutting-edge sample treatment technique offering significant advantages in terms of miniaturization, green character, automation, and preconcentration prior to analysis. During the past years, there has been a considerable increase in the reported publications, as well as in the research groups focusing their activities on this technique. In the present review article, HPLC bioanalytical applications of in-tube SPME are discussed, covering a wide time frame of twenty years of research reports. Instrumental aspects towards the coupling of in-tube SPME and HPLC are also discussed, and detailed information on materials/coatings and applications in biological samples are provided.

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“…The benefits of sample preparation do not only involve sample clean-up, but also preconcentration of the target analytes (Farajzadeh et al, 2016;Vichapong et al, 2016;Moyakao et al, 2018;Kachangoon et al, 2020). Currently, several sample extraction techniques, such as cloud point extraction (CPE) (Kachangoon et al, 2020), liquid-phase microextraction (LLME) Jovanov et al, 2013;Bolzan et al, 2015;Vichapong et al, 2015;Hou et al, 2019;Kachangoon et al, 2020) solid-phase extraction (SPE) (Xie et al, 2011;Shi et al, 2017;Zhang et al, 2017;Cao et al, 2018;Moyakao et al, 2018;Xiong et al, 2018;Hou et al, 2019) and solid-phase microextraction (SPME) (Ding et al, 2019;Queiroz et al, 2019;Xue et al, 2019), have been reported for the extraction of the neonicotinoid insecticides in various samples. Among the SPE based methods magnetic solid-phase extraction (MSPE) has gained a lot of attention due to its attractive properties such as simplicity, rapidity, robustness, high enrichment factors, and environmentally friendliness (Deng et al, 2009(Deng et al, , 2019Wang et al, 2018b;Queiroz et al, 2019).…”

Section: Introductionmentioning

confidence: 99%

Magnetic Solid Phase Extraction Based on Nanostructured Magnetic Porous Porphyrin Organic Polymer for Simultaneous Extraction and Preconcentration of Neonicotinoid Insecticides From Surface Water

et al. 2020

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In this study, a magnetic porphyrin-based porous organic polymer (MP-POP) nanocomposite was successfully synthesized according previous studies and applied as an adsorbent for simultaneous extraction and preconcentration of four neonicotinoid insecticides from surface river water. The MP-POP was characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy/energy dispersive x-ray spectroscopy (SEM/EDS), N 2-adsorption/desorption analysis, Fourier Transform infrared spectroscopy (FTIR). The neonicotinoid insecticides were quantified using high performance chromatography coupled with diode array detector (HPLC-DAD). The MP-POP shown to have a high surface area, highly porous structure and strong affinity toward the investigated analytes. The adsorption capacities were 99.0, 85.5, 90.0, and 79.4 mg g −1 for acetamiprid, clothiandin, thiacloprid and imidacloprid, respectively. The influential parameters affecting the magmatic µ-solid phase extraction (M-µ-SPE) procedure were investigated using fractional factorial design and surface response methodology (RSM). Under optimum conditions, the method exhibited relatively low limit of detection in the range of 1.3-3.2 ng L −1 , limit of quantification in the range of 4.3-11 ng L −1 and wide linearity (up to 600 µg L −1). The intraday and interday precision, expressed as the relative standard deviation (RSD) were <5%. The percentage recoveries for the four target analytes ranged from 91 to 99.3% for the spiked river water samples. The method was applied for determination of neonicotinoids in river water samples and concentrations ranged from 0 to 190 ng L −1 .

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Current advances and applications of in-tube solid-phase microextraction

Cited by 113 publications

References 53 publications

Metal–Organic Frameworks as Key Materials for Solid-Phase Microextraction Devices—A Review

Metal–Organic Frameworks as Key Materials for Solid-Phase Microextraction Devices—A Review

Bioanalytical HPLC Applications of In-Tube Solid Phase Microextraction: A Two-Decade Overview

Magnetic Solid Phase Extraction Based on Nanostructured Magnetic Porous Porphyrin Organic Polymer for Simultaneous Extraction and Preconcentration of Neonicotinoid Insecticides From Surface Water

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