Curing Agent for High-Concentration Unclassified Tailings Stockpiling: A Case Study of Tailings from a Gold Mine

Abstract

The disposal of tailings has always been a focal point in the mining industry. Semi-dry tailings stockpiling, specifically high-concentration tailings stockpiling, has emerged as a potential solution. To enhance the stability of tailings stockpiling and minimize its costs, the incorporation of a low-cost curing agent into high-concentration tailings is essential. Therefore, this study focuses on the development of a curing agent for high-concentration unclassified tailings stockpiling. The composition of a low-cost curing agent system is determined based on theoretical analysis, and the curing reaction mechanisms of each composition are researched. Subsequently, an orthogonal experiment is designed, and the strength of the modified unclassified tailings solidified samples at different curing ages is measured. Furthermore, the rheological properties of the modified unclassified tailings slurries are tested, and the feasibility of industrial transportation of the unclassified tailings slurries modified with the optimized curing agent is analyzed. Lastly, the microscopic morphologies of each material and the modified unclassified tailings solidified samples are characterized, their chemical compositions are tested, and the action mechanism of the curing agent in the curing system is further investigated. The results show that the optimal proportions of each material in the curing agent are as follows: slag, 58%; quicklime, 15%; cement, 8%; gypsum, 9%; and bentonite, 10%. The dominance of industrial waste slag exceeding 50% reflects the low-cost nature of the curing agent. Under this condition, the modified unclassified tailings slurry with a mass concentration of 75% exhibited a yield stress of 43.62 Pa and a viscosity coefficient of 0.67 Pa·s, which is suitable for pipeline transportation. These findings lay a foundation for subsequent decisions regarding stockpiling processes and equipment selection.