2009
DOI: 10.1080/03602550902824473
|View full text |Cite
|
Sign up to set email alerts
|

Cure Kinetic of Poly (alkyltetrasulfide) Using a Rheological Method

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

1
7
0
1

Year Published

2011
2011
2020
2020

Publication Types

Select...
6

Relationship

0
6

Authors

Journals

citations
Cited by 14 publications
(11 citation statements)
references
References 23 publications
1
7
0
1
Order By: Relevance
“…[57] The high chemical resistance of the polymers also meant a lack of suitable solvents for solution processing, thus limiting the further application of the chemistry outside industrial applications of compression-molded articles. [58] Readily processable polysulfide polymers were desired, as the labile S À S bonds in these materials could be utilized for an array of applications, including polymeric chain-transfer agents [59] and high-energy-content solid polymer fuels. [60] Recently, various soluble polycondensates of polysulfide anions and organic dihalides were reported (Scheme 1).…”
Section: Angewandte Minireviewsmentioning
confidence: 99%
“…[57] The high chemical resistance of the polymers also meant a lack of suitable solvents for solution processing, thus limiting the further application of the chemistry outside industrial applications of compression-molded articles. [58] Readily processable polysulfide polymers were desired, as the labile S À S bonds in these materials could be utilized for an array of applications, including polymeric chain-transfer agents [59] and high-energy-content solid polymer fuels. [60] Recently, various soluble polycondensates of polysulfide anions and organic dihalides were reported (Scheme 1).…”
Section: Angewandte Minireviewsmentioning
confidence: 99%
“…e total activation energy of crosslinking reaction can be obtained from the t gel . It was assumed that the curing reaction can be described by using a differential equation, which included an apparent activation energy, as follows [25]:…”
Section: Resultsmentioning
confidence: 99%
“…According to Flory's gelation theory [25], the reaction degree at a gelation point should remain constant at different reaction temperatures. From α � 0 to α � α gel , the following formula was obtained for the equation integration [25,26]:…”
Section: Resultsmentioning
confidence: 99%
“…Die hohe chemische Beständigkeit der Polymere bedeutet andererseits, dass es kaum geeignete Lösungsmittel für ihre Weiterverarbeitung in Lösung gibt. Abgesehen von industriellen Verarbeitungsmethoden wie Spritzgussverfahren war somit die chemische Weiterverarbeitung lange Zeit eingeschränkt 58. Einfach zu verarbeitende Polysulfidpolymere sind von Interesse, da ihre labilen S‐S‐Bindungen für eine Reihe von Anwendungen genutzt werden könnten, z.…”
Section: Chemische Umwandlung Von Elementarem Schwefelunclassified