Cubic Hafnium Nitride: A Novel Topological Semimetal Hosting a 0-Dimensional (0-D) Nodal Point and a 1-D Topological Nodal Ring

Li, Yang; Xia, Jihong

doi:10.3389/fchem.2020.00727

Cited by 7 publications

(5 citation statements)

References 63 publications

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“…Very recently, tetragonal PtO was proposed by Li et al (2020b) as an effective material to study the one-dimensional nodal line and zero-dimensional nodal point states. Furthermore, Li and Xia (2020) predicted that cubic HfN is a topological material that co-exhibits nodal line and nodal loop states.…”

Section: Introductionmentioning

confidence: 99%

Hexagonal Zr3X (X = Al, Ga, In) Metals: High Dynamic Stability, Nodal Loop, and Perfect Nodal Surface States

Gao

2020

Front. Chem.

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In recent years, topological semimetals/metals, including nodal point, nodal line, and nodal surface semimetals/metals, have been studied extensively because of their potential applications in spintronics and quantum computers. In this study, we predict a family of materials, Zr 3 X (X = Al, Ga, In), hosting the nodal loop and nodal surface states in the absence of spin-orbit coupling. Remarkably, the energy variation of the nodal loop and nodal surface states in Zr 3 X are very small, and these topological signatures lie very close to the Fermi level. When the effect of spin-orbit coupling is considered, the nodal loop and nodal surface states exhibit small energy gaps (<25 and 35 meV, respectively) that are suitable observables that reflect the spin-orbit coupling response of these topological signatures and can be detected in experiments. Moreover, these compounds are dynamically stable, and they consequently form potential material platforms to study nodal loop and nodal surface semimetals.

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Section: Introductionmentioning

confidence: 99%

Hexagonal Zr3X (X = Al, Ga, In) Metals: High Dynamic Stability, Nodal Loop, and Perfect Nodal Surface States

Gao

2020

Front. Chem.

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“…HfN exhibits mechanical attributes such as hardness and wear resistance and is used as a coating on highend equipment for protection [17,18]. However, there is a lack of literature on this novel coating HfN, requiring basic to advanced evaluations of their surface topography and other properties favorable for dental implantology [15].…”

Section: Introductionmentioning

confidence: 99%

Analyzing the Surface Topography of Hafnium Nitride Coating on Titanium Screws: An In Vitro Analysis

Jose,

Rajaraman,

Ariga

et al. 2024

Cureus

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Background The use of surface coatings to enhance the properties lacking in titanium has attracted significant focus in recent times. Hafnium nitride (HfN) coatings could be explored as promising in the osteoinductive properties of titanium implants. HfN exhibits excellent mechanical attributes, such as hardness and wear resistance, and is often used as a coating on high-end equipment for protection. The findings from this research may carve a new path for the production and optimization of HfN coatings to enhance the longevity and augment properties of implant materials. Thus, the present study was orchestrated to elucidate the surface morphology of HfN coating, ultimately contributing to the advancement of dental implant biomaterials. Materials and methods A total of twenty samples of medical grade commercially pure titanium screws (2 mm diameter and 7 mm length) were procured from G. R. Bioure Surgical System Pvt. Ltd., Ravali, Uttar Pradesh, India, and ten samples were reacted with HfN (0.1 M) (Nano Research Elements, Kurukshetra, Haryana, India) in 100% ethanol and stirred continuously for about 48 hours. Then these screw samples were immersed in the prepared colloidal suspension and sintered for two hours at 400 degrees centigrade. The implant screws were affixed onto metal supports. The magnifications for photomicrographs at ×30, ×200, ×1,500, ×3,000, and ×5,000 were standardized. Elementary semi-quantitative analysis of both dental implants was conducted using energy-dispersive X-ray spectrometry (EDX) coupled with the field emission scanning electron microscope (FE-SEM) equipment (JEOL Ltd., Akishima, Tokyo, Japan). The software used for the analysis of the obtained images is SEM Center. Results The surface analysis using the scanning electron microscope (SEM) showed the coating of HfN over titanium screws. The difference in surface morphology of both the group of implant screws can be visualized under 40.0 and 10.0 mm working distance (WD) for both groups. The surface analysis using the EDX of uncoated titanium screws shows five elements in the spectrum: titanium (Ti), oxygen (O), aluminum (Al), carbon (C), and vanadium (V). The EDX of the HfN-coated screws has two additional metals dispersed in the spectrum, hafnium (Hf). The element characteristics are tabulated with their apparent concentration, k ratio, line type, weight percentage, standard label, and factory label for uncoated titanium screws and HfN-coated titanium screws. Conclusion The study evaluated HfN coating over medical grade commercially pure titanium. The surface topography of coated versus uncoated was visualized. The scanning electron microscope (SEM) images showed a homogenous coating over the titanium surfaces, and the EDX showed elemental dispersion of the coated implant. The study aims to provide a comprehensive understanding of the coating's surface morphology, which will aid in the development of more durable and biocompatible implants. This there...

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“…Topological semimetals [1][2][3][4][5][6][7][8][9][10] with symmetry-protected bands crossing around the Fermi level have inspired enormous interest in condensed matter physics. As a typical family of topological semimetals, node-line semimetals [11][12][13][14][15][16][17][18][19][20] have high band degeneracy along a certain line in the Brillouin zone (BZ), and the resultant drumhead surface states at the boundary. Suppose more than one nodal line/ring appears in momentum space.…”

Section: Introductionmentioning

confidence: 99%

Ideal nodal net phonons in Pn3¯m type Ag2O

2023

Front. Phys.

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The topological phonon state is a new field that has sparked much interest. Weyl phonons in FeSi, for example, have been theoretically proposed and experimentally identified. In this work, via the first-principle calculation, we prove the ideal nodal net phonons exist in a realistic material Ag2O with Pn3¯m type structure. With the help of the Berry phase calculations, we find that the nodal net phonons in Ag2O are topologically non-trivial. The phononic surface states are visible, which benefits the experimental detections. The results in this work contribute to the material realization of topological nodal net phonons. The author hopes the experimental verification of the novel topological phonons can be performed in the following investigations.

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Cubic Hafnium Nitride: A Novel Topological Semimetal Hosting a 0-Dimensional (0-D) Nodal Point and a 1-D Topological Nodal Ring

Cited by 7 publications

References 63 publications

Hexagonal Zr3X (X = Al, Ga, In) Metals: High Dynamic Stability, Nodal Loop, and Perfect Nodal Surface States

Hexagonal Zr3X (X = Al, Ga, In) Metals: High Dynamic Stability, Nodal Loop, and Perfect Nodal Surface States

Analyzing the Surface Topography of Hafnium Nitride Coating on Titanium Screws: An In Vitro Analysis

Ideal nodal net phonons in Pn3¯m type Ag2O

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