Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

Cu 3(SeO4)2(SeO3OH)2(H2O)16 -The First Example of a Linear Octahedral--Tetrahedral Heptamer in InorganicCompounds. -Single crystals of the new copper selenate Cu 3(SeO4)2(SeO3OH) 2(H2O)16 are obtained by hydrothermal reaction of an aqueous solution of (UO2)NO3, Cu(NO3)2, and H2SeO4 (autoclave, 180 C, 72 h) followed by slow solvent evaporation. The compound crystallizes in the triclinin space group P1 with Z = 1. The title heptamers are formed by successive polymerization of two SeO 3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)4O2 octahedra. The octahedra and tetrahedra are linked in trans-configuration which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu 2+ . -(GURZHIY, V. V.; AL-SHURAY, A.; BRITVIN, S. N.; KRIVOVICHEV*, S. V.; Eur. J. Inorg. Chem. 2015, 32, 5311-5313, http://dx.

show abstract

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

Gurzhiy

Al-Shuray

Britvin

et al. 2016

ChemInform

View full text Add to dashboard Cite

show abstract

Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

Kovrugin

Colmont

Siidra

et al. 2017

Journal of Crystal Growth

View full text Add to dashboard Cite

Dehydration-driven evolution of topological complexity in ethylamonium uranyl selenates

Gurzhiy

Krivovichev

Тананаев

2017

Journal of Solid State Chemistry

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Cu₃(SeO₄)₂(SeO₃OH)₂(H₂O)₁₆ – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

Cited by 7 publications

References 31 publications

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

Dehydration-driven evolution of topological complexity in ethylamonium uranyl selenates

Contact Info

Product

Resources

About

Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

Cited by 7 publications

References 31 publications

ChemInform Abstract: Cu3(SeO4)2(SeO3OH)2 (H2O)16 — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

ChemInform Abstract: Cu3(SeO4)2(SeO3OH)2 (H2O)16 — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

Dehydration-driven evolution of topological complexity in ethylamonium uranyl selenates

Contact Info

Product

Resources

About

Cu₃(SeO₄)₂(SeO₃OH)₂(H₂O)₁₆ – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.