Cu−NPs@C Nanosheets Derived from a PVP‐assisted 2D Cu‐MOF with Renewable Ligand for High‐Efficient Selective Hydrogenation of 5‐Hydroxymethylfurfural

Bao, Liwei; Yang, Shan-Qing; Hu, Tong‐Liang

doi:10.1002/cssc.202200392

Cited by 5 publications

(3 citation statements)

References 57 publications

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“…The ligand is essential to the preparation of MOFs, and a large number of ligands are derived from non-renewable fossil resources. Bao et al (Bao et al 2022 ) employed renewable HMF-derived 2,5-furandicarboxylic acid as ligand to synthesize a novel Cu-based MOFs, and Cu NPs supported on carbon nanosheets were fabricated by post-treatment of the MOFs. The as-prepared Cu catalysts exhibited good catalytic activity and stability for the hydrogenation of HMF to FDM, providing a 99.4% yield.…”

Section: Synthesis Of Fdm From Hmfmentioning

confidence: 99%

Recent advances in catalytic synthesis of 2,5-furandimethanol from 5-hydroxymethylfurfural and carbohydrates

Du,

Yang,

Cao

et al. 2023

Bioresour. Bioprocess.

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Abstract5-Hydroxymethylfurfural (HMF) is a versatile platform chemical derived from the dehydration of renewable carbohydrates (typically glucose/fructose-based monosaccharides, oligosaccharides, and polysaccharides). Some useful compounds, such as 2,5-furandimethanol (FDM), 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF), have been synthesized by reduction of HMF. Among these, FDM is a promising diol and can be further converted towards fine chemicals, liquid fuels and polymer materials. In this review, some typical catalytic systems for the synthesis of FDM from both HMF and carbohydrates were summarized. The discussion focused on controlling the reaction networks for the reduction of HMF. The reaction mechanisms and the stability of the catalysts were introduced briefly. Last but not least, the prospects of effective production of FDM were discussed as well.

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Section: Synthesis Of Fdm From Hmfmentioning

confidence: 99%

Recent advances in catalytic synthesis of 2,5-furandimethanol from 5-hydroxymethylfurfural and carbohydrates

Du,

Yang,

Cao

et al. 2023

Bioresour. Bioprocess.

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show abstract

“…[140] Bao et al also reported that a 2D oxygen-rich carbon nanosheets embedded with Cu nanoparticles (Cu-NPs@C) prepared via pyrolysis of nano-lamellae Cu-FDC exhibited excellent performance and stability for the selective hydrogenation of HMF to DHMF (see Figure 15B). [141] Wu and co-workers disclosed that small Pd nanoparticles could be stabilized in MOF-303 by the adjacent pair of N atoms of organic linkers (Pd@MOF-303), and the yield of DHMTHF was 95.8 % under 1 MPa H 2 due to the exposure of plenty of stable defective sites on Pd nanoparticles. [142] Karve et al had developed a palladium-functionalized MOF/polymer composite, Reproduced with permission from ref.…”

Section: (B)mentioning

confidence: 99%

Metal Organic Frameworks Derived Catalysts for the Upgrading of Platform Chemicals

Zhao,

Du,

Hou

2023

ChemCatChem

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Biomass plays a significant role in replacing fossil resources, and catalytic transformation of platform chemicals to high‐value chemicals is an effective approach to maximize the utilization of biomass. Among of which, efficient and durable catalysts are the heart for upgrading of these platform chemicals, and metal–organic frameworks (MOFs)‐derived catalysts have attracted much attentions due to their suitable and versatile physicochemical properties. In this work, we present a short review on the applications of MOFs‐derived catalysts in upgrading of platform chemicals. The design and synthetic strategies of MOFs‐derived catalysts were summarized in detail, and their application in the catalytic upgrading of glycerol, ethanol, furanic compounds, levulinic acid and vanillin were addressed. The final section outlines the potential industrial applications of MOFs‐derived catalysts for upgrading platform chemicals.

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“…Nevertheless, compared to the classical ligand, H 2 FDC-related MOFs are still relatively few, with only about 100 associated reports. Also, the applications of such MOFs are mainly focused on luminescence, − gas adsorption, − and catalysis, − and only one MOF related to proton conductivity has been involved …”

Section: Introductionmentioning

confidence: 99%

Syntheses and High Proton Conductivities of Two 3D Zr(IV)/Hf(IV)-MOFs from Furandicarboxylic Acid

Chen

et al. 2023

Inorg. Chem.

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With the gradual progress of research on proton-conducting metal–organic framework (MOFs), it has become a challenging task to find MOF materials that are easy to prepare and have low toxicity, high stability, and splendid proton conductivity. With the abovementioned objectives in mind, we selected the non-toxic organic ligand 2,5-furandicarboxylic acid and the low toxic quadrivalent metals zirconium(IV) or hafnium(IV) as starting materials and successfully obtained 2 three-dimensional porous MOFs, [M6O4(OH)4(FDC)4(OH)4(H2O)4] [M = ZrIV (1) and HfIV (2)], with ultrahigh water stability using a rapid and green synthesis approach. Their proton conductive ability is remarkable, thanks to the large number of Lewis acidic sites contained in their porous frameworks and the abundant H-bonding network, hydroxyl groups, as well as coordination and crystalline water molecules. The positive correlation of their proton conductivity with relative humidity (RH) and the temperature was observed. Notably, their optimized proton conductivities are 2.80 × 10–3 S·cm–1 of 1 and 3.38 × 10–3 S·cm–1 of 2 under 100 °C/98% RH, which are at the forefront of Zr(IV)/Hf(IV) MOFs with prominent proton conductivity. Logically, their framework features, nitrogen/water adsorption/desorption data, and activation energy values are integrated to deduce their proton conductivity and conducting mechanism differences.

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Cu−NPs@C Nanosheets Derived from a PVP‐assisted 2D Cu‐MOF with Renewable Ligand for High‐Efficient Selective Hydrogenation of 5‐Hydroxymethylfurfural

Cited by 5 publications

References 57 publications

Recent advances in catalytic synthesis of 2,5-furandimethanol from 5-hydroxymethylfurfural and carbohydrates

Recent advances in catalytic synthesis of 2,5-furandimethanol from 5-hydroxymethylfurfural and carbohydrates

Metal Organic Frameworks Derived Catalysts for the Upgrading of Platform Chemicals

Syntheses and High Proton Conductivities of Two 3D Zr(IV)/Hf(IV)-MOFs from Furandicarboxylic Acid

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