Cu-Metalated Porphyrin-Based MOFs Coupled with Anatase as Photocatalysts for CO2 Reduction: The Effect of Metalation Proportion
Maria Anagnostopoulou,
Valérie Keller,
Konstantinos C. Christoforidis
Abstract:Converting carbon dioxide (CO2) into valuable chemicals such as fossil resources via photocatalysis requires the development of advanced materials. Herein, we coupled zirconium-based metal–organic frameworks (MOFs) containing porphyrin and Cu-porphyrin with anatase TiO2. The effect of the porphyrin metalation proportion was also investigated. Notably, while the use of free-base porphyrin as the organic linker resulted in the development of PCN-224, the presence of Cu-porphyrin provided mixed-phase MOF structur… Show more
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