Cu-Graphene water-based hybrid nanofluids: synthesis, stability, thermophysical characterization, and figure of merit analysis

Abstract

Hybrid nanofluids are emerging as an alternative to conventional heat transfer fluids and nanofluids for improving the thermal efficiency of heat exchanging devices synergistically due to their outstanding thermophysical properties associated because of the dispersion of different types of nanoparticles as compared to mono nanofluids. This will help in optimizing fluid characteristics in different flow regimes for several applications. However, enhancing the thermal energy efficiency of heat exchangers is challenging owing to the deprived stability of hybrid nanofluids at greater volume concentrations. This work concentrated on the synthesizing, thermophysical depiction, and thermal performance estimation of stable water-based Cu-graphene hybrid nanofluids using very low volume concentrations of Cu and graphene hybrid nanostructures. Cu-graphene hybrid nanofluid was successfully synthesized by dispersing the synthesized Cu and graphene nanostructures (keeping the Cu concentration constant at 0.04 vol % and varying the graphene concentration from 0.01 to 0.1 vol %) in water. Hybrid nanofluids display excellent stability against aggregation for up to 7 weeks, as proven by higher zeta potential values. Thermophysical characteristics of the prepared hybrid nanofluids were effectively measured. The thermal conductivity of Cu-graphene hybrid nanofluids shows exceptional enrichment (~ 35%) at minimal concentrations of hybrid nanostructures. Viscosity of the water-based hybrid nanofluids shows remarkable enhancement as compared to water and represents the increasing trend in viscosity of the base fluid with respect to the increase in concentration of hybrid nanostructures. The thermal and rheological properties of hybrid nanofluids are effectively validated with existing theoretical models. In addition, the specific heat and pumping power of Cu-graphene hybrid nanofluids with respect to the volume concentration of hybrid nanostructures are calculated using the existing theoretical equations. A figure of merit (FOM) analysis was conducted for the synthesized hybrid nanofluids to gauge thermal efficiency and evaluate the applicability of these hybrid nanofluids under laminar and turbulent flow conditions.