2016
DOI: 10.1080/13640461.2016.1142233
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Crystallography of graphite spheroids in cast iron

Abstract: International audienceTo further understand graphite growth mechanisms in cast irons, this study focuses on the crystal structure of a graphite spheroid in the vicinity of its nucleus. A sample of a graphite spheroid from a commercial cast iron was characterised using transmission electron microscopy. The chemical composition of the nucleating particle was studied at the local scale. Crystal orientation maps of the graphite spheroid revealed misorientations and twist boundaries. High resolution lattice fringei… Show more

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Cited by 6 publications
(7 citation statements)
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“…Based on previous observations [9] and literature review, it has already been pointed out that nuclei may have a rounded shape and be amorphous [6]. In the present study, the rounded nucleus seen in Fig.…”
Section: Discussionsupporting
confidence: 73%
“…Based on previous observations [9] and literature review, it has already been pointed out that nuclei may have a rounded shape and be amorphous [6]. In the present study, the rounded nucleus seen in Fig.…”
Section: Discussionsupporting
confidence: 73%
“…A last note concerning Figure 2 is that graphite developed as sectors right at the surface of the nucleus, but no epitaxy could be found between any of the dark crystalline precipitates and the graphite around. 17 This suggests that graphite could certainly nucleate on any heterogeneous substrate and that the most important step in the nodularizing process is graphite growth as already pointed out by various authors. 10,11 This will be further elaborated in the next section.…”
Section: Graphite Nucleationmentioning
confidence: 74%
“…Figure 2 shows the nucleus of a graphite spheroid found in an industrial nodular cast iron. 17 This nucleus consists mainly of (Ca,Mg)S, but is amorphous and was certainly liquid when graphite nucleated. As mentioned above, several small particles of crystalline phases can be seen at the periphery of this nucleus.…”
Section: Graphite Nucleationmentioning
confidence: 99%
“…The formation of white cast iron was eluded, injection of magnesium additions makes graphite nodular in shape and ferrosilicon promotes graphitization during solidification. As compared to flaky graphite in grey cast iron, spheroidal graphite does not weaken the matrix significantly; hence, the mechanical properties are of better quality compared to the grey iron [12].…”
Section: Materials Melting Processesmentioning
confidence: 97%