2006
DOI: 10.1016/j.jallcom.2005.11.058
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Crystallization kinetics of ultrafine Co74.4B25.6 amorphous powder prepared by chemical reduction

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Cited by 16 publications
(8 citation statements)
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“…4 is the DSC plots for samples S6, S7 and S8 taken at a heating rate of 20 K/min. It is noted that no distinguished glass transition was identified on these curves, which is in agreement with the previous results [8,9] that the samples were also prepared by chemical reduction. All these curves have a single exothermic peak, which further confirms that these three samples were indeed amorphous, and suggests that their crystallization occurred in a single-stage process corresponding to the simultaneous precipitation of crystalline phases.…”
Section: Composition and Structuresupporting
confidence: 92%
“…4 is the DSC plots for samples S6, S7 and S8 taken at a heating rate of 20 K/min. It is noted that no distinguished glass transition was identified on these curves, which is in agreement with the previous results [8,9] that the samples were also prepared by chemical reduction. All these curves have a single exothermic peak, which further confirms that these three samples were indeed amorphous, and suggests that their crystallization occurred in a single-stage process corresponding to the simultaneous precipitation of crystalline phases.…”
Section: Composition and Structuresupporting
confidence: 92%
“…TEM results confirmed that the particle size of these catalysts was very small, especially for the modified NiCoB catalysts. It has been reported that the amorphous nano-sized catalysts have many intrinsic properties such as short-range order, long-range disorder, and more defect sites [21][22][23][24][25][26]. These properties favored their catalytic properties.…”
Section: Discussionmentioning
confidence: 99%
“…6 observation, we know that the thermal stability of Co-Zr-B amorphous powder rests with Co-based Zr-containing amorphous particles. It has been found that the addition of Zr element to the Co-B alloy system increases the crystallization peak temperature up to 771.3 K compared to the Co 74.4 B 25.6 amorphous powders prepared by chemical reduction, for which the one and only crystallization peak temperature is 737.7 K [28]. An amorphous alloy can be regarded as a kind of supercooled liquid.…”
Section: Structure and Thermal Stabilitymentioning
confidence: 99%