“…They occur in obsidian domes, vitrophyric ash-flow tuffs (e.g., Smith et al 2001), largevolume rhyolite flows such as those at Yellowstone (e.g., Wright, 1915), and in shallow volcanic conduits (e.g., Stasiuk et al, 1993;Tuffen and Castro, 2009). Spherulites nucleate and grow in response to large undercoolings (>200°C) rapidly imposed on the magma by its degassing and quenching (e.g., Swanson et al, 1989). As dictated by the thermal profile of a magma body (Manley, 1992;Tuffen et al, in review), spherulitic obsidian develops in spatially restricted zones (e.g., Manley and Fink, 1987;Stevenson et al 1994), comprising a transitional facies that separates the rapidly quenched, outermost vitrophyric rhyolite from a devitrified microcrystalline core.…”