Crystallization and Magnetic Behavior of Manganese(II) 4,4′-Benzophenone Dicarboxylates and a Comparison of Its Structural Landscape with 2,4′-Benzophenone Dicarboxylate
Bharti Singh,
Kaumudi Yadav,
Balendra
et al.
Abstract:Exploration of the structural landscape of the system Mn(II) salt−4,4′-benzophenone dicarboxylic acid−N-donor based auxiliary ligand−solvent using high-throughput solvothermal reaction led to the isolation of seven new coordination polymers (CPs): [Mn(phen)(H 2 O)(4,4′-bpdc) 2 ] 1, [Mn 3 (2,2′-bipy) 2 (4,4′-bpdc) 3 ]•solvent (solvent = DMA, DMF, and DMSO for 2, 3, and 4, respectively), [Mn 3 (4,4′-dimethyl-2,2′-bipy) 2 (4,4′-bpdcA single-crystal X-ray diffraction study revealed that the presence of phen led to… Show more
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