2002
DOI: 10.1016/s0032-3861(02)00239-2
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Crystallinity measurements of polyamides adsorbed as thin films

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Cited by 63 publications
(59 citation statements)
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“…These peaks can probably be related to the stretch vibration of the Si-O-Si group of the clay, since the contributions of PA6 in this particular area are very small. In addition, it was noticed a slight increase in the intensity of these peaks, which can be related to the increase in clay content, used in the preparation of hybrid membranes [38][39][40][41][42] . Also in Figure 2, it was observed typical characteristic bands of formic acid: a broadband at 3300 cm -1 , related to the axial deformation of the O-H group; at 2940 and 2860 cm -1 there are bands related to axial strain of C-H group, which is superimposed with the band of O-H group; and at 1640 cm -1 , there is the axial deformation of the C=O group; the region of 1420 cm -1 is in agreement with the angular deformation of the C-O-H group; at 1256 cm -1 there is a band related to the axial strain of the C-O group and also involves interactions with C-O-H group.…”
Section: Water Permeability and Oil Retentionmentioning
confidence: 98%
“…These peaks can probably be related to the stretch vibration of the Si-O-Si group of the clay, since the contributions of PA6 in this particular area are very small. In addition, it was noticed a slight increase in the intensity of these peaks, which can be related to the increase in clay content, used in the preparation of hybrid membranes [38][39][40][41][42] . Also in Figure 2, it was observed typical characteristic bands of formic acid: a broadband at 3300 cm -1 , related to the axial deformation of the O-H group; at 2940 and 2860 cm -1 there are bands related to axial strain of C-H group, which is superimposed with the band of O-H group; and at 1640 cm -1 , there is the axial deformation of the C=O group; the region of 1420 cm -1 is in agreement with the angular deformation of the C-O-H group; at 1256 cm -1 there is a band related to the axial strain of the C-O group and also involves interactions with C-O-H group.…”
Section: Water Permeability and Oil Retentionmentioning
confidence: 98%
“…In the past, most Raman studies have concerned only the middle wavenumber range, the bending domain and stretching modes [18][19][20][21][22][23]. Information obtained from these modes is very local.…”
Section: Choice Of the Raman Probesmentioning
confidence: 99%
“…These low wavenumber collective modes may be preferred for the study of the relationship between the chain structure and the macroscopic mechanical behaviour. On the other hand, the assignments of bending and stretching modes are well documented, especially their relationship with conformational changes [18][19][20][21][22][23][24][25][26][27][28][29][30][31]. Note, local modes such as N-H stretching mode can also a good source of information about the modification of neighbouring chains arrangements [9][10][11]16,17].…”
Section: Choice Of the Raman Probesmentioning
confidence: 99%
“…It may be possible to develop techniques to determine the localization of active compounds by fluorescence emission in confocal microscopy 76,77 or by infrared mapping. [78][79][80][81][82] • Properties. The most important property of CRP is the release kinetics.…”
Section: S Y S T E M R E L a T I O N S H I P Smentioning
confidence: 99%