Efficient mid IR (1.5-2.2 µm) Raman lasers based on novel BaWO 4 and known Ba(NO 3 ) 2 Raman crystals were developed and investigated. Different Stokes shifted components were obtained with longest wavelength about 2.2 µm with efficiency up to 10%.
Main informationNowadays great attention is paid to the development of novel lasers oscillating in mid IR spectral range (2-5 µm) where the lack of laser sources (especially within 3-5 µm range) is quite noticeable. There are several approaches towards development of laser sources for mid IR spectral region: development of new solid state laser media, molecular gas lasers, OPO generators etc. One of the promising approaches is Raman shifting of the available laser sources towards mid IR range. The main problem here is that most of the Raman crystals' frequency shift is about 1000 cm −1 , so to obtain mid IR radiation one should start from as long wavelength as possible and obtain second or even third Stokes shifted components. At the same time it should be kept in mind that Raman gain drops rapidly with longer wavelength pump, so that stimulated Raman scattering threshold intensities become separated from the crystal optical damage threshold intensities by rather narrow interval making Raman lasing a sort of challenge. Another problem for mid IR Raman lasing is that a lot of well known efficient Raman crystals are opaque in this spectral range due to the matrix absorption.The newly developed barium tungstate crystals are proved to be efficient source for both picosecond and nanosecond time scale Raman lasing [1]. Our results on stimulated Raman scattering under nanosecond IR pumping in comparison with the well-known barium nitrate crystal showed rather close thresholds and conversion efficiency. Though BaWO 4 crystals are much further transparent and allows obtaining Raman shifted radiation up to 3 µm.As the initial pump source the 1.34 µm YAG:Nd 3+ laser and 1.53 µm Er:Glass laser were applied. These lasers were selected due to their longest lasing wavelengths where short Q-switched pulses can be rather reliably obtained. In our experiments accousto-optically Qswitching for Nd:YAG laser and passive Q-switching by Co 2+ :spinel crystal for Er:Glass laser were applied which allowed to obtain pulses with 40-50 ns duration in both cases. This lasers served as pump sources for 80 mm long BaWO 4 crystal or 50 mm long Ba(NO 3 ) 2 crystal based Raman lasers with the cavity formed by a rear plain HR mirror with 90-100% reflectivity within oscillating spectral range and about 80% transmittance at pumping wavelengths. To optimize first, second or third Stokes