Crystalline Electronic Field in Rare-Earth Based Quasicrystal and Approximant: Analysis of Quantum Critical Au-Al-Yb Quasicrystal and Approximant
Shinji Watanabe,
Mina Kawamoto
Abstract:On the basis of the point charge model, we formulate the crystalline electronic field (CEF) Hamiltonian H CEF in the rare-earth based quasicrystal (QC) and approximant crystal (AC) with ligand ions located at pseudo 5-fold configurations by using the operator equivalent method. By setting the total angular momentum J = 7/2, the CEF in the quantum critical QC Au 51 Al 34 Yb 15 and the 1/1 AC Au 51 Al 35 Yb 14 is analyzed with consideration for the effect of Al/Au mixed sites. We find that the ratio of the valen… Show more
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