Crystal structures of two dis-symmetric di-Schiff base compounds: 2-({(E)-2-[(E)-2,6-dichlorobenzylidene]hydrazin-1-ylidene}methyl)-6-methoxyphenol and 4-bromo-2-({(E)-2-[(E)-2,6-dichlorobenzylidene]hydrazin-1-ylidene}methyl)phenol
Abstract:Each of the title dis-symmetric di-Schiff base compounds, C15H12Cl2N2O2 (I) and C14H9BrCl2N2O (II), features a central azo-N—N bond connecting two imine groups, each with an E-configuration. One imine bond in each molecule connects to a 2,6-dichlorobenzene substituent while the other links a 2-hydroxyl-3-methoxy-substituted benzene ring in (I) or a 2-hydroxyl-4-bromo benzene ring in (II). Each molecule features an intramolecular hydroxyl-O—H...N(imine) hydrogen bond. The C—N—N—C torsion angles of −151.0 (3)° f… Show more
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