Crystal structures of seven mixed-valence gold compounds of the form [(R1R2R3PE)2AuI]+[AuIIIX4]− (R = tert-butyl or isopropyl, E = S or Se, and X = Cl or Br)
Daniel Upmann,
Dirk Bockfeld,
Peter G. Jones
et al.
Abstract:During our studies of the oxidation of gold(I) complexes of trialkylphosphane chalcogenides, general formula R
1
R
2
R
3PEAuX, (R = tert-butyl or isopropyl, E = S or Se, X = Cl or Br) with PhICl2 or elemental bromine, we have isolated a set of seven mixed-valence by-products, the bis(trialkylphosphane chalcogenido)gold(I) tetrahalogenidoaurates(III) [(R
1
R
2
… Show more
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