Crystal structures of a novel NNN pincer ligand and its dinuclear titanium(IV) alkoxide pincer complex

Abstract

The title compound is an LiBr-bridged TiIV alkoxide dimer, supported by a novel monoanionic [NNN] pincer-type ligand. The bis­[2-(1-imino-2,2-di­methyl­prop­yl)-4-methyl­phen­yl]amine ligand is the first reported ligand that bears hydrogen atoms on its ketimine side arms.