Crystal structure, spectroscopic measurement, optical properties, thermal studies and biological activities of a new hybrid material containing iodide anions of bismuth(iii)

Abstract

A novel halogenobismuthate(iii) organic–inorganic hybrid material named bis(4,4′-diammoniumdiphenylsulfone) hexadecaiodotetrabismuthate(iii) tetrahydrate, (C12H14N2O2S)2[Bi4I16]·4H2O, has been prepared by slow evaporation at room temperature.

One-Year Water-Stable and Porous Bi(III) Halide Semiconductor with Broad-Spectrum Antibacterial Performance

“…This gives rise to bond angle variance values of 37.65 and 18.34 deg 2 for [Bi(2)­I 6 ] 3– and [Bi(1)­I 6 ] 3– octahedra. Interestingly, the corresponding tetramer is the same as in the case of (C 12 H 14 N 2 O 2 S) 2 [Bi 4 I 16 ]·4H 2 O compound . Notably, Bi–I bond lengths and I–Bi–I angles match closely among the two materials.…”

“…52,53 Notably, bismuth metal halides have emerged recently as promising antibacterial candidates. 55 Aygun et al synthesized a series of bismuth(III) halides with benzaldehyde-N 1 -alkyl-thiosemicarbazone that were found to be most active against E. coli. 56 Ozturk et al demonstrated that bismuth(III) thiosemicarbazone complexes, such as BiCl 3 (η 1 -S-Hacptsc) 3 (Hacptsc = acetophenone thiosemicarbazone), exhibited toxicity against MCF-7 and MRC-5 cells, and antibacterial activity against E. coli and P. aeruginosa.…”

“…coli, Listeria monocytogenes, Salmonella enterica, MRSA, Micrococcusluteus , Bacillus cereus, Enterobacter aeruginosa, and P. aeruginosa . Aygun et al synthesized a series of bismuth­(III) halides with benzaldehyde- N 1 -alkyl-thiosemicarbazone that were found to be most active against E.…”

Building Stable Solid‐State Potassium Metal Batteries

“…[ 43 ] Meanwhile, Raman spectroscopy was also used to characterize the ISPE (Figure S7, Supporting Information). The vibrational stretching I 3 − mode at 112 cm −1 , and the peaks at 56 and 132 cm −1 corresponded to Bi–I–PEO complexes, [ 44‐47 ] which represents the interaction between K 4 BiI 7 and the PEO substrate. In addition, the inductively coupled plasma data of ISPE revealed the presence of Bi 3+ in the modified PEO (Figure S8, Supporting Information), confirming the complexation of the K 4 BiI 7 filler with the PEO substrate.…”

A novel antibacterial benzimidazolium hexachlorotellurate hybrid compound: Experimental-theoretical characterization

“…Furthermore, the presence of chlorine in the structure boosts its ability to inhibit the multiplication of E. coli and Staph, so it can be considered like a bacteriostatic substance. This antibacterial property makes T3 more attractive compared to similar hybrid materials that showed a low reaction against these bacteria such as (C 12 H 14 N 2 O 2 S) 2 [Bi 4 I 16 ]⋅4H 2 O and (C 10 H 28 N 4 )[CoCl 4 ] 2 [94,95].…”