Crystal structure of the salt bis(triethanolamine-κ3N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Ashurov, Jamshid; Obidova, Nodira; Abdireymov, Hudaybergen B.; Ибрагимов, Б. Т.

doi:10.1107/s2056989016002930

Cited by 3 publications

(1 citation statement)

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“…We have reported the synthesis of mixed-ligand complexes of Zn, Cd and Cu with TEA and p-nitrobenzoic acid (NBA) (Ashurov et al, 2015). The cobalt(II) complex [Co(C 6 H 15 NO 3 ) 2 ](C 9 H 6 NO 3 S) 2 , obtained by the reaction of NBTA and TEA with Co(NO 3 ) 2 , has been reported (Ashurov et al, 2016). Here, the synthesis and structure of the related title compound, [Cd(C 6 H 15 NO 3 ) 2 ](C 9 H 6 NO 3 S) 2 , (I), is described.…”

Section: Chemical Contextmentioning

confidence: 99%

Crystal structure of the salt bis(triethanolamine-κ⁴N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Ashurov

2016

Acta Cryst E

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Section: Chemical Contextmentioning

confidence: 99%

Crystal structure of the salt bis(triethanolamine-κ⁴N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Ashurov

2016

Acta Cryst E

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New cobalt(II) coordination complex for adsorption of Rhodamine B dye and its mechanistic pathway

Bhatti,

Qasim,

Imran

et al. 2024

Inorganica Chimica Acta

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Crystal Structure and Hirshfeld Surface Analysis of Bis(Triethanolamine)Nickel(II) Dinitrate Complex and a Revelation of Its Characteristics via Spectroscopic, Electrochemical and DFT Studies Towards a Promising Precursor for Metal Oxides Synthesis

et al. 2020

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Metal complexes with chelating ligands are known as promising precursors for the synthesis of targeted metal oxides via thermal decomposition pathways. Triethanolamine (TEA) is a versatile ligand possessing a variety of coordination modes to metal ions. Understanding the crystal structure is beneficial for the rational design of the metal complex precursors. Herein, a bis(triethanolamine)nickel (II) dinitrate (named as Ni-TEA) crystal was synthesized and thoroughly investigated. X-ray crystallography revealed that Ni(II) ions adopt a distorted octahedral geometry surrounded by two neutral TEA ligands via two N and four O coordinates. Hirshfeld surface analysis indicated the major contribution of the intermolecular hydrogen-bonding between —OH groups of TEA in the crystal packing. Moreover, several O–H stretching peaks in Fourier transformed infrared spectroscopy (FTIR) spectra emphasizes the various chemical environments of —OH groups due to the formation of the hydrogen-bonding framework. The Density-functional theory (DFT) calculation revealed the electronic properties of the crystal. Furthermore, the Ni-TEA complex is presumably useful for metal oxide synthesis via thermal decomposition at a moderate temperature (380 °C). Cyclic voltammetry indicated the possible oxidative reaction of the Ni-TEA complex at a lower potential than nickel(II) nitrate and TEA ligand, highlighting its promising utility for the synthesis of mixed valence oxides such as spinel structures.

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Crystal structure of the salt bis(triethanolamine-κ³N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Cited by 3 publications

References 30 publications

Crystal structure of the salt bis(triethanolamine-κ⁴N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Crystal structure of the salt bis(triethanolamine-κ⁴N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

New cobalt(II) coordination complex for adsorption of Rhodamine B dye and its mechanistic pathway

Crystal Structure and Hirshfeld Surface Analysis of Bis(Triethanolamine)Nickel(II) Dinitrate Complex and a Revelation of Its Characteristics via Spectroscopic, Electrochemical and DFT Studies Towards a Promising Precursor for Metal Oxides Synthesis

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Crystal structure of the salt bis(triethanolamine-κ3N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Cited by 3 publications

References 30 publications

Crystal structure of the salt bis(triethanolamine-κ4N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Crystal structure of the salt bis(triethanolamine-κ4N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

New cobalt(II) coordination complex for adsorption of Rhodamine B dye and its mechanistic pathway

Crystal Structure and Hirshfeld Surface Analysis of Bis(Triethanolamine)Nickel(II) Dinitrate Complex and a Revelation of Its Characteristics via Spectroscopic, Electrochemical and DFT Studies Towards a Promising Precursor for Metal Oxides Synthesis

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About

Crystal structure of the salt bis(triethanolamine-κ³N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Crystal structure of the salt bis(triethanolamine-κ⁴N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]

Crystal structure of the salt bis(triethanolamine-κ⁴N,O,O′,O′′)cadmium bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]