Abstract:Forty years ago, application of the Mannich reaction to the synthesis of aminomethylphosphines developed a new research area for the synthesis of novel phosphine ligands. 1,2 The syntheses of some macrocyclic multidentate crown-ethers and podands containing P-C-N linkages have been reported. 3,4 The title ligand was prepared from a mixture of triethylene glycol bis(2-aminophenyl ether) 5 (2.66 g, 8.00 mmol), diphenylphosphine (5.54 mL, 32.0 mmol) and formaldehyde (7.00 mL, 37% solution in water) in benzene (15… Show more
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